data_global
_chemical_name_mineral 'Oxykinoshitalite'
loop_
_publ_author_name
'Kogarko L N'
'Uvarova Y A'
'Sokolova E'
'Hawthorne F C'
'Ottolini L'
'Grice J D'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 43 
_journal_year 2005
_journal_page_first 1501
_journal_page_last 1510
_publ_section_title
;
 Oxykinoshitalite, a new species of mica from Fernando-do-Noronha island, Brazil:
 Occurrence and crystal structure
;
_database_code_amcsd 0006061
_chemical_compound_source 'Fernando-do-Noronha island, Brazil'
_chemical_formula_sum 'Ba.47 K.42 Na.06 Ca.01 Mg1.36 Fe.88 Ti.75 Mn.01 Si2.312 Al1.56 O11.75 F.25 H.31'
_cell_length_a 5.3516
_cell_length_b 9.2817
_cell_length_c 10.0475
_cell_angle_alpha 90
_cell_angle_beta 100.337
_cell_angle_gamma 90
_cell_volume 490.978
_exptl_crystal_density_diffrn      3.392
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
BaI   0.00000   0.00000   0.00000   0.47000   0.02290
KI   0.00000   0.00000   0.00000   0.42000   0.02290
NaI   0.00000   0.00000   0.00000   0.06000   0.02290
CaI   0.00000   0.00000   0.00000   0.01000   0.02290
MgM1   0.00000   0.50000   0.50000   0.52000   0.01020
Fe2+M1   0.00000   0.50000   0.50000   0.13000   0.01020
Fe3+M1   0.00000   0.50000   0.50000   0.27000   0.01020
Ti4+M1   0.00000   0.50000   0.50000   0.08000   0.01020
MgM2   0.00000   0.15509   0.50000   0.42000   0.01270
Ti4+M2   0.00000   0.15509   0.50000   0.33500   0.01270
Fe3+M2   0.00000   0.15509   0.50000   0.16500   0.01270
Fe2+M2   0.00000   0.15509   0.50000   0.07500   0.01270
MnM2   0.00000   0.15509   0.50000   0.00500   0.01270
SiT   0.57360   0.16750   0.22032   0.57800   0.01110
AlT   0.57360   0.16750   0.22032   0.39000   0.01110
O1   0.81790   0.23540   0.15860   1.00000   0.02270
O2   0.63140   0.17090   0.39030   1.00000   0.01350
O3   0.52230   0.00000   0.16030   1.00000   0.02020
O4   0.12570   0.00000   0.39640   0.72000   0.01600
O-H4   0.12570   0.00000   0.39640   0.15500   0.01600
F4   0.12570   0.00000   0.39640   0.12500   0.01600
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
BaI 0.01970 0.02050 0.02850 0.00000 0.00460 0.00000
KI 0.01970 0.02050 0.02850 0.00000 0.00460 0.00000
NaI 0.01970 0.02050 0.02850 0.00000 0.00460 0.00000
CaI 0.01970 0.02050 0.02850 0.00000 0.00460 0.00000
MgM1 0.00820 0.00650 0.01670 0.00000 0.00430 0.00000
Fe2+M1 0.00820 0.00650 0.01670 0.00000 0.00430 0.00000
Fe3+M1 0.00820 0.00650 0.01670 0.00000 0.00430 0.00000
Ti4+M1 0.00820 0.00650 0.01670 0.00000 0.00430 0.00000
MgM2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000
Ti4+M2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000
Fe3+M2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000
Fe2+M2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000
MnM2 0.00670 0.01750 0.01390 0.00000 0.00140 0.00000
SiT 0.00830 0.01060 0.01450 -0.00050 0.00240 0.00010
AlT 0.00830 0.01060 0.01450 -0.00050 0.00240 0.00010
O1 0.01920 0.02870 0.02100 -0.00750 0.00600 -0.00300
O2 0.01200 0.01070 0.01800 -0.00070 0.00310 0.00070
O3 0.02900 0.01630 0.01300 0.00000 -0.00120 0.00000
O4 0.00930 0.02300 0.01600 0.00000 0.00310 0.00000
O-H4 0.00930 0.02300 0.01600 0.00000 0.00310 0.00000
F4 0.00930 0.02300 0.01600 0.00000 0.00310 0.00000