data_global
_chemical_name_mineral 'Gladite'
loop_
_publ_author_name
'Petricek V'
'Makovicky E'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 44 
_journal_year 2006
_journal_page_first 189
_journal_page_last 206
_publ_section_title
;
 Interpretation of selected structures of the bismuthinite - aikinite series as
 commensurately modulated structures
 Sample: oversubstituted gladite
;
_database_code_amcsd 0006078
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Cu.388 Pb.398 Bi1.602 S3'
_cell_length_a 4.0100
_cell_length_b 11.1963
_cell_length_c 11.502
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 516.407
_exptl_crystal_density_diffrn      6.921
_symmetry_space_group_name_H-M 'P m c n'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2-x,y,z'
  '1/2+x,-y,-z'
  '1/2+x,1/2+y,1/2-z'
  '1/2-x,1/2-y,1/2+z'
  'x,1/2-y,1/2+z'
  '-x,1/2+y,1/2-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Cu1   0.25000   0.71410   0.72060   0.25000   0.04260
Cu2   0.25000   0.70570   0.73240   0.13800   0.04000
PbM2   0.25000   0.52284   0.33716   0.39750   0.04163
BiM2   0.25000   0.52284   0.33716   0.60250   0.04163
BiM1   0.25000   0.17793   0.51838   1.00000   0.03650
S1   0.25000  -0.05630   0.37820   1.00000   0.03300
S2   0.25000   0.63170   0.54730   1.00000   0.03440
S3   0.25000   0.30520   0.71580   1.00000   0.03240