data_global
_amcsd_formula_title 'U8Cs2Se4Co3O52'
loop_
_publ_author_name
'Wylie E M'
'Burns P C'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 50 
_journal_year 2012
_journal_page_first 147
_journal_page_last 157
_publ_section_title
;
 Crystal structures of six new uranyl selenate and selenite compounds and
 their relationship with uranyl mineral structures
 Note: Compound 2
;
_database_code_amcsd 0019086
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Cs Co1.5 U4 Se2 O26 H4'
_cell_length_a 8.744
_cell_length_b 14.380
_cell_length_c 17.901
_cell_angle_alpha 90
_cell_angle_beta 103.654
_cell_angle_gamma 90
_cell_volume 2187.238
_exptl_crystal_density_diffrn      5.318
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Cs  -0.02890   0.75410   0.50661   0.50000   0.02580
Co1  -0.50000   0.75010   0.25000   0.50000   0.00800
Co2  -0.06920   0.74960   0.36730   0.50000   0.04150
U1   0.41430   0.98142   0.33236   1.00000   0.00760
U2  -0.08501   0.01863   0.33301   1.00000   0.00780
Se   0.24980   0.99138   0.50090   1.00000   0.01280
O1   0.35200   0.00620   0.20650   1.00000   0.01700
O2   0.18200   0.92280   0.55810   1.00000   0.01400
O3   0.42000   0.10080   0.36410   1.00000   0.01400
O4   0.11900   0.05900   0.44800   1.00000   0.01800
O5  -0.08100   0.89860   0.36590   1.00000   0.01300
O6   0.38200   0.05940   0.55270   1.00000   0.01400
O7   0.31700   0.92430   0.44170   1.00000   0.01800
O8  -0.14700   0.99450   0.20500   1.00000   0.01000
Wat9  -0.29500   0.75260   0.33700   1.00000   0.02600
O10  -0.06800   0.74400   0.21300   0.50000   0.11000
O11   0.41700   0.85580   0.31170   1.00000   0.01500
O12  -0.08400   0.14320   0.31270   1.00000   0.01000
O13  -0.11700   0.75500   0.47900   0.50000   0.06400
O14   0.15380   0.74760   0.37000   1.00000   0.01200
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Cs 0.04120 0.00970 0.02600 0.00900 0.00700 -0.00130
Co2 0.04400 0.03400 0.05000 -0.00300 0.01600 -0.00400
U1 0.00750 0.01050 0.00500 -0.00100 0.00180 -0.00320
U2 0.00700 0.01100 0.00560 -0.00100 0.00200 -0.00310
Se 0.00970 0.01900 0.01000 0.00080 0.00290 0.00510