data_global _chemical_name_mineral 'Uedaite-(Ce)' loop_ _publ_author_name 'Miyawaki R' 'Yokoyama K' 'Matsubara S' 'Tsutsumi Y' 'Goto A' _journal_name_full 'European Journal of Mineralogy' _journal_volume 20 _journal_year 2008 _journal_page_first 261 _journal_page_last 269 _publ_section_title ; Uedaite-(Ce), a new member of the epidote group with Mn at the A site, from Shodoshima, Kagawa Prefecture, Japan ; _database_code_amcsd 0007258 _chemical_compound_source 'Shodoshima Island, Kagawa Prefecture, western Japan' _chemical_formula_sum '(Mn.65 Ca.35) Ce.914 Fe1.1 Al1.986 Si3 O13 H' _cell_length_a 8.865 _cell_length_b 5.717 _cell_length_c 10.060 _cell_angle_alpha 90 _cell_angle_beta 114.520 _cell_angle_gamma 90 _cell_volume 463.873 _exptl_crystal_density_diffrn 4.196 _symmetry_space_group_name_H-M 'P 1 21/m 1' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2-y,z' '-x,1/2+y,-z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv MnA1 0.75371 0.75000 0.14962 0.65000 0.01620 CaA1 0.75371 0.75000 0.14962 0.35000 0.01620 CeA2 0.59398 0.75000 0.42960 0.91400 0.01294 FeA2 0.59398 0.75000 0.42960 0.08600 0.01294 AlM1 0.00000 0.00000 0.00000 0.87300 0.01100 FeM1 0.00000 0.00000 0.00000 0.12700 0.01100 AlM2 0.00000 0.00000 0.50000 0.98800 0.00950 FeM2 0.00000 0.00000 0.50000 0.01200 0.00950 FeM3 0.30676 0.25000 0.21065 0.87500 0.01200 AlM3 0.30676 0.25000 0.21065 0.12500 0.01200 Si1 0.34062 0.75000 0.03426 1.00000 0.01020 Si2 0.68819 0.25000 0.27847 1.00000 0.00990 Si3 0.19042 0.75000 0.32381 1.00000 0.00900 O1 0.23240 0.99020 0.01840 1.00000 0.01740 O2 0.31610 0.97280 0.36540 1.00000 0.01350 O3 0.79980 0.01180 0.33140 1.00000 0.01640 O4 0.05880 0.25000 0.12910 1.00000 0.01350 O5 0.05270 0.75000 0.15180 1.00000 0.01510 O6 0.07510 0.75000 0.41760 1.00000 0.01260 O7 0.51020 0.75000 0.17880 1.00000 0.01720 O8 0.54760 0.25000 0.33860 1.00000 0.02340 O9 0.60030 0.25000 0.09940 1.00000 0.02000 O-H10 0.08900 0.25000 0.43000 1.00000 0.01220 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 MnA1 0.02560 0.00950 0.01660 0.00000 0.01200 0.00000 CaA1 0.02560 0.00950 0.01660 0.00000 0.01200 0.00000 CeA2 0.01143 0.01346 0.01223 0.00000 0.00321 0.00000 FeA2 0.01143 0.01346 0.01223 0.00000 0.00321 0.00000 AlM1 0.00990 0.00710 0.01470 -0.00060 0.00380 0.00010 FeM1 0.00990 0.00710 0.01470 -0.00060 0.00380 0.00010 AlM2 0.00780 0.00640 0.01330 0.00000 0.00350 -0.00070 FeM2 0.00780 0.00640 0.01330 0.00000 0.00350 -0.00070 FeM3 0.01020 0.00960 0.01300 0.00000 0.00150 0.00000 AlM3 0.01020 0.00960 0.01300 0.00000 0.00150 0.00000 Si1 0.00970 0.00720 0.01210 0.00000 0.00280 0.00000 Si2 0.00950 0.00730 0.01270 0.00000 0.00430 0.00000 Si3 0.00850 0.00770 0.01040 0.00000 0.00350 0.00000 O1 0.01390 0.00940 0.02720 0.00260 0.00690 -0.00080 O2 0.01340 0.01000 0.01670 -0.00290 0.00570 -0.00050 O3 0.01280 0.00840 0.02040 0.00160 -0.00070 -0.00070 O4 0.01250 0.01120 0.01450 0.00000 0.00350 0.00000 O5 0.01510 0.01280 0.01560 0.00000 0.00450 0.00000 O6 0.01560 0.00870 0.01880 0.00000 0.01230 0.00000 O7 0.01620 0.01550 0.01460 0.00000 0.00100 0.00000 O8 0.01510 0.03700 0.01790 0.00000 0.00630 0.00000 O9 0.01910 0.02600 0.01490 0.00000 0.00690 0.00000 O-H10 0.01170 0.00890 0.02000 0.00000 0.01060 0.00000