data_global
_chemical_name_mineral 'Hoganite'
loop_
_publ_author_name
'Meester P'
'Fletcher S R'
'Skapski A C'
_journal_name_full 'Dalton Transactions'
_journal_volume 1973 
_journal_year 1973
_journal_page_first 2575
_journal_page_last 2578
_publ_section_title
;
 Refined crystal structure of tetra-mu-acetato-bisaquodicopper (II)
;
_database_code_amcsd 0012426
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Cu C4 H8 O5'
_cell_length_a 13.168
_cell_length_b 8.564
_cell_length_c 13.858
_cell_angle_alpha 90
_cell_angle_beta 117.02
_cell_angle_gamma 90
_cell_volume 1392.197
_exptl_crystal_density_diffrn      1.905
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Cu   0.45004   0.08401   0.04496 ?
C1   0.68240  -0.02140   0.18040 ?
C2   0.78370  -0.03800   0.28880 ?
C3   0.43320  -0.24770   0.05070 ?
C4   0.39610  -0.39630   0.08360 ?
H1   0.76700  -0.04400   0.35700   0.01900
H2   0.84300  -0.08800   0.29200   0.01900
H3   0.81500   0.06900   0.31200   0.01900
H4   0.41500  -0.38500   0.16200   0.01900
H5   0.43900  -0.48100   0.06500   0.01900
H6   0.31300  -0.40400   0.04800   0.01900
H7   0.39000   0.16800   0.19500   0.01900
H8   0.31800   0.27300   0.10800   0.01900
O1   0.68360  -0.08810   0.10060 ?
O2   0.60000   0.06030   0.17590 ?
O3   0.49220  -0.26470  -0.00030 ?
O4   0.40540  -0.12010   0.07530 ?
O-h5   0.37570   0.20730   0.13300 ?
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Cu 0.01903 0.02560 0.01807 0.00102 0.01174 0.00021
C1 0.02440 0.03233 0.02239 -0.00051 0.01247 0.00268
C2 0.03207 0.07022 0.02625 0.01374 0.00587 -0.00536
C3 0.02440 0.03084 0.02702 -0.00560 0.01100 0.00536
C4 0.04253 0.03567 0.04710 -0.00967 0.02421 0.01339
O1 0.01952 0.03864 0.02007 0.00458 0.01027 -0.00107
O2 0.02231 0.03827 0.01853 0.00560 0.00880 -0.00321
O3 0.04043 0.02564 0.04015 -0.00305 0.02788 0.00161
O4 0.03207 0.02824 0.03861 -0.00102 0.02421 0.00696
O-h5 0.04531 0.04347 0.03011 0.02087 0.03008 0.01125