data_global
_amcsd_formula_title 'Ba Bi Cu La O6 Pb'
loop_
_publ_author_name
'Pham A'
'Michel C'
'Hervieu M'
'Maignan A'
'Raveau B'
_journal_name_full 'Journal of Physics and Chemistry of Solids'
_journal_volume 54 
_journal_year 1993
_journal_page_first 65
_journal_page_last 71
_publ_section_title
;
 Substitution of lead for bismuth in the 2201-type oxide
 Bi2BaLaCuO6+d
 _cod_database_code 1001550
;
_database_code_amcsd 0013237
_chemical_formula_sum 'Bi Pb (Ba La) Cu O6'
_cell_length_a 5.4028
_cell_length_b 5.4745
_cell_length_c 24.515
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 725.096
_exptl_crystal_density_diffrn      7.804
_symmetry_space_group_name_H-M 'F m m m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
  '1/2+x,y,1/2+z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  'x,1/2-y,1/2+z'
  '1/2+x,-y,1/2+z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '-x,1/2+y,1/2-z'
  '1/2-x,y,1/2-z'
  '1/2-x,1/2+y,-z'
  '-x,y,z'
  '-x,1/2+y,1/2+z'
  '1/2-x,y,1/2+z'
  '1/2-x,1/2+y,z'
  'x,-y,-z'
  'x,1/2-y,1/2-z'
  '1/2+x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  'x,y,-z'
  'x,1/2+y,1/2-z'
  '1/2+x,y,1/2-z'
  '1/2+x,1/2+y,-z'
  '-x,-y,z'
  '-x,1/2-y,1/2+z'
  '1/2-x,-y,1/2+z'
  '1/2-x,1/2-y,z'
  '-x,-y,-z'
  '-x,1/2-y,1/2-z'
  '1/2-x,-y,1/2-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Bi1   0.03300   0.00000   0.18970   0.25000
Pb1   0.03300   0.00000   0.18970   0.25000
Ba1   0.00000   0.00000   0.42470   0.50000
La1   0.00000   0.00000   0.42470   0.50000
Cu1   0.00000   0.00000   0.00000   1.00000
O1   0.25000   0.25000   0.00000   1.00000
O2   0.00000   0.00000   0.09680   1.00000
O3   0.09400   0.11000   0.30670   0.25000