data_global _chemical_name_mineral 'Lazurite' loop_ _publ_author_name 'Evsyunin V G' 'Sapozhnikov A N' 'Kashaev A A' 'Rastsvetaeva R K' _journal_name_full 'Kristallografiya' _journal_volume 42 _journal_year 1997 _journal_page_first 1014 _journal_page_last 1021 _publ_section_title ; Crystal structure of triclinic lazurite Loclaity: Malaya-Bystray deposit, Lake Baikal, Russia ; _database_code_amcsd 0014196 _chemical_formula_sum 'Na28 Ca4 Si24 Al24 S8.49 O119' _cell_length_a 9.067 _cell_length_b 12.896 _cell_length_c 25.708 _cell_angle_alpha 89.98 _cell_angle_beta 90.08 _cell_angle_gamma 90.22 _cell_volume 3005.960 _exptl_crystal_density_diffrn 2.376 _symmetry_space_group_name_H-M 'P 1' loop_ _space_group_symop_operation_xyz 'x,y,z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv Na1 0.80860 0.31420 0.24890 1.00000 0.02660 Na2 0.30730 0.18210 0.24980 1.00000 0.03420 Na3 0.16010 0.50690 0.15450 1.00000 0.03166 Na4 0.17960 0.49400 0.34440 1.00000 0.04179 Na5 0.69790 0.82390 0.74780 1.00000 0.02533 Na6 0.22540 0.49280 0.86190 1.00000 0.03673 Na7 0.21390 0.18780 0.50630 1.00000 0.03040 Na8 0.26520 0.49210 0.63580 1.00000 0.03040 Na9 0.81270 0.19040 0.00370 1.00000 0.03293 Na10 0.22560 0.21680 0.99820 1.00000 0.03546 Na11 0.34420 0.99590 0.65830 1.00000 0.02786 Na12 0.80340 0.21780 0.49760 1.00000 0.04306 Na13 0.19940 0.68940 0.74870 1.00000 0.02406 Na14 0.65830 0.00570 0.15850 1.00000 0.02660 Na15 0.84380 0.49690 0.65680 1.00000 0.02153 Na16 0.84620 0.00310 0.59780 1.00000 0.02660 Na17 0.16100 0.00030 0.00930 1.00000 0.03040 Na18 0.77400 0.51270 0.36000 1.00000 0.03166 Na19 0.78210 0.81180 0.00510 1.00000 0.02786 Na20 0.82980 0.50940 0.84240 1.00000 0.02786 Na21 0.19430 0.81380 0.50470 1.00000 0.02786 Na22 0.19480 0.79010 0.99530 1.00000 0.03040 Na23 0.77710 0.78080 0.49570 1.00000 0.03293 Na24 0.74400 0.50830 0.13520 1.00000 0.02786 CaM1 0.31100 0.24320 0.75340 0.75000 0.02153 NaM1 0.31100 0.24320 0.75340 0.25000 0.02153 CaM2 0.70160 0.75610 0.25200 0.55000 0.02406 NaM2 0.70160 0.75610 0.25200 0.45000 0.02406 CaM3 0.75750 0.00520 0.87670 0.75000 0.02026 NaM3 0.75750 0.00520 0.87670 0.25000 0.02026 CaM4 0.22670 0.75950 0.25060 0.45000 0.02406 NaM4 0.22670 0.75950 0.25060 0.55000 0.02406 CaM5 0.78130 0.24730 0.75100 0.25000 0.02406 NaM5 0.78130 0.24730 0.75100 0.75000 0.02406 CaM6 0.71840 0.00190 0.36950 0.50000 0.01900 NaM6 0.71840 0.00190 0.36950 0.50000 0.01900 CaM7 0.23560 -0.00080 0.37730 0.50000 0.03293 NaM7 0.23560 -0.00080 0.37730 0.50000 0.03293 CaM8 0.28160 0.99920 0.86910 0.25000 0.02406 NaM8 0.28160 0.99920 0.86910 0.75000 0.02406 Si1 0.24380 0.24840 0.37380 1.00000 0.01013 Si2 0.74850 0.25780 0.37400 1.00000 0.00887 Si3 0.27640 0.25810 0.87660 1.00000 0.01013 Si4 0.55500 0.37730 0.68830 1.00000 0.01013 Si5 0.50420 0.87490 0.93690 1.00000 0.01140 Si6 0.48530 0.37420 0.18730 1.00000 0.01013 Si7 0.97850 0.62490 0.44020 1.00000 0.00887 Si8 0.04820 0.12150 0.68720 1.00000 0.00887 Si9 0.54360 0.12110 0.56330 1.00000 0.01013 Si10 0.04840 0.37710 0.56040 1.00000 0.01393 Si11 0.27130 0.75000 0.62540 1.00000 0.01140 Si12 0.46370 0.62080 0.31270 1.00000 0.00760 Si13 0.97080 0.87590 0.31250 1.00000 0.00760 Si14 0.99010 0.62550 0.93470 1.00000 0.01013 Si15 0.98900 0.37440 0.06570 1.00000 0.00887 Si16 0.76780 0.75170 0.62700 1.00000 0.01140 Si17 0.77900 0.24710 0.87810 1.00000 0.00633 Si18 0.48260 0.87920 0.43980 1.00000 0.00887 Si19 0.48530 0.12690 0.06600 1.00000 0.00887 Si20 0.50560 0.62890 0.80950 1.00000 0.01013 Si21 0.70860 0.75250 0.12640 1.00000 0.01013 Si22 0.01020 0.87550 0.81070 1.00000 0.01140 Si23 0.20940 0.75170 0.12240 1.00000 0.01013 Si24 -0.01840 0.13090 0.18690 1.00000 0.00760 Al1 0.49530 0.13020 0.43750 1.00000 0.01013 Al2 0.54600 0.38280 0.81510 1.00000 0.00760 Al3 0.02270 0.37640 0.94160 1.00000 0.01140 Al4 -0.00680 0.12720 0.31060 1.00000 0.01013 Al5 0.79490 0.25070 0.62320 1.00000 0.01013 Al6 0.01140 0.37570 0.43610 1.00000 0.01140 Al7 0.29880 0.24680 0.62610 1.00000 0.01013 Al8 0.49710 0.37300 0.31100 1.00000 0.01013 Al9 0.51630 0.12650 0.94090 1.00000 0.01140 Al10 0.73410 0.25390 0.12660 1.00000 0.00887 Al11 0.03180 0.12540 0.81250 1.00000 0.00760 Al12 0.23650 0.24690 0.12690 1.00000 0.00887 Al13 0.72040 0.74720 0.37610 1.00000 0.01013 Al14 0.75250 0.75400 0.87110 1.00000 0.01140 Al15 0.02350 0.87130 0.68610 1.00000 0.00887 Al16 0.52020 0.62760 0.68580 1.00000 0.01140 Al17 0.52040 0.87330 0.56530 1.00000 0.01140 Al18 0.01720 0.62830 0.56570 1.00000 0.01140 Al19 0.25280 0.74490 0.87370 1.00000 0.01140 Al20 0.22140 0.75140 0.37880 1.00000 0.00887 Al21 0.96090 0.62480 0.06010 1.00000 0.01267 Al22 -0.03990 0.88080 0.18650 1.00000 0.01140 Al23 0.45610 0.62260 0.18630 1.00000 0.01013 Al24 0.46650 0.87890 0.06300 1.00000 0.01267 S1 0.98540 0.00230 0.48500 1.00000 0.01900 S2 0.05440 0.46680 0.75120 1.00000 0.01646 S3 0.53060 0.03330 0.76210 1.00000 0.02660 S4 0.95620 0.53570 0.25090 1.00000 0.02406 S5 0.01240 0.99830 0.98510 1.00000 0.01900 S6 0.47320 -0.03030 0.26130 1.00000 0.02660 S7 0.55400 0.48400 -0.01900 0.89000 0.33689 S8 0.43600 0.62100 0.02200 0.82000 0.23177 S9 0.45100 0.53600 0.48600 0.48000 0.26344 S10 0.44000 0.38200 0.48200 0.30000 0.13298 O1 0.52740 0.35240 0.75110 1.00000 0.01013 O2 0.12780 0.15060 0.14980 1.00000 0.01520 O3 0.03830 0.34720 0.50230 1.00000 0.01520 O4 0.95300 -0.00130 0.32400 1.00000 0.01900 O5 0.43150 0.49170 0.17450 1.00000 0.02280 O6 0.44210 0.50040 0.32340 1.00000 0.01267 O7 0.53650 0.35760 0.24730 1.00000 0.01267 O8 0.35280 0.29000 0.32660 1.00000 0.01773 O9 0.66100 0.34850 0.34540 1.00000 0.01520 O10 0.83570 0.19550 0.32680 1.00000 0.01520 O11 0.35340 0.29860 0.17720 1.00000 0.00633 O12 0.03890 0.34880 0.00490 1.00000 0.01900 O13 0.14640 0.15920 0.34450 1.00000 0.02026 O14 0.17670 0.33470 0.90840 1.00000 0.02026 O15 0.18770 0.18550 0.83280 1.00000 0.02153 O16 0.62720 0.15290 0.10230 1.00000 0.01646 O17 0.97120 0.85420 0.75090 1.00000 0.01140 O18 0.45590 0.64340 0.75000 1.00000 0.01646 O19 0.12540 0.35060 0.10510 1.00000 0.01267 O20 0.87210 0.65260 0.60650 1.00000 0.01773 O21 -0.06930 0.00860 0.17560 1.00000 0.01773 O22 0.84300 0.20300 0.17640 1.00000 0.01140 O23 0.90880 0.16100 0.65340 1.00000 0.01900 O24 0.34140 0.20120 0.07660 1.00000 0.01900 O25 0.62720 0.35020 0.15030 1.00000 0.01773 O26 0.18960 0.31610 0.58190 1.00000 0.02406 O27 0.38790 0.32980 0.84240 1.00000 0.01520 O28 0.00940 0.15010 0.74790 1.00000 0.01013 O29 0.69740 0.31820 0.66800 1.00000 0.02406 O30 0.60630 0.66980 0.33980 1.00000 0.02026 O31 0.03710 0.15230 0.24590 1.00000 0.01646 O32 0.36810 0.65220 0.64620 1.00000 0.01900 O33 0.51480 0.14800 0.50520 1.00000 0.02406 O34 0.43390 0.01030 0.07650 1.00000 0.01900 O35 0.84410 0.30290 0.07610 1.00000 0.02406 O36 0.63190 0.83180 0.41800 1.00000 0.02026 O37 0.33090 0.19050 0.41880 1.00000 0.01393 O38 0.04600 0.99340 0.82300 1.00000 0.01773 O39 0.11270 0.83710 0.15540 1.00000 0.02153 O40 0.07250 0.49850 0.57420 1.00000 0.01900 O41 0.15250 0.80760 0.82550 1.00000 0.01900 O42 0.64290 0.70760 0.82310 1.00000 0.01520 O43 0.68660 0.18610 0.57850 1.00000 0.02153 O44 0.48250 -0.00070 0.42270 1.00000 0.01773 O45 0.64720 0.17120 0.40080 1.00000 0.02153 O46 0.61080 0.67190 0.15900 1.00000 0.02153 O47 0.35540 0.64640 0.84280 1.00000 0.02153 O48 0.19860 0.17990 0.67450 1.00000 0.02026 O49 0.37100 0.84340 0.60320 1.00000 0.01393 O50 0.11190 0.83550 0.34140 1.00000 0.01773 O51 0.30350 0.69070 0.16430 1.00000 0.02026 O52 0.17060 0.79070 0.67260 1.00000 0.01646 O53 0.98270 0.84980 0.25260 1.00000 0.01900 O54 0.15360 0.34200 0.39460 1.00000 0.01267 O55 0.86570 0.85000 0.84240 1.00000 0.01773 O56 0.39230 0.15380 0.59460 1.00000 0.02533 O57 0.47020 0.85810 0.50300 1.00000 0.02280 O58 0.83320 0.67310 0.41300 1.00000 0.02026 O59 0.93500 0.49370 0.07370 1.00000 0.02533 O60 0.56570 0.50050 0.67500 1.00000 0.01520 O61 0.87510 0.16760 0.84450 1.00000 0.02153 O62 0.40180 0.33640 0.66110 1.00000 0.01393 O63 0.66650 0.70930 0.67330 1.00000 0.01646 O64 0.86910 0.84910 0.64790 1.00000 0.01520 O65 0.67150 0.79200 0.57760 1.00000 0.01900 O66 0.16830 0.70950 0.57790 1.00000 0.01900 O67 0.65710 0.82680 0.91800 1.00000 0.01773 O68 0.66610 0.17480 0.90740 1.00000 0.02533 O69 0.89410 0.34580 0.59010 1.00000 0.02153 O70 0.06900 -0.00050 0.67540 1.00000 0.01646 O71 0.33580 0.83240 0.41230 1.00000 0.02153 O72 0.61700 0.83810 0.09560 1.00000 0.02533 O73 0.56520 0.51400 0.82290 1.00000 0.01520 O74 0.81740 0.82500 0.33180 1.00000 0.02153 O75 0.31300 0.67360 0.33230 1.00000 0.02280 O76 0.57460 -0.00140 0.57470 1.00000 0.02280 O77 0.01150 0.50610 0.92400 1.00000 0.02153 O78 0.80670 0.69190 0.08390 1.00000 0.02406 O79 0.53390 0.15040 0.00680 1.00000 0.02913 O80 0.70440 0.33040 0.83900 1.00000 0.02026 O81 0.12520 0.68170 0.42430 1.00000 0.03040 O82 0.95530 0.65520 0.99360 1.00000 0.02660 O83 0.85020 0.30500 0.41730 1.00000 0.02406 O84 0.51250 -0.00290 0.92330 1.00000 0.01900 O85 0.35340 0.18220 0.91960 1.00000 0.01773 O86 0.48080 0.85980 0.99770 1.00000 0.03293 O87 0.85340 0.65700 0.89850 1.00000 0.02026 O88 0.36240 0.83460 0.90720 1.00000 0.03040 O89 0.80070 0.81640 0.16830 1.00000 0.01773 O90 0.98530 0.50560 0.42390 1.00000 0.02280 O91 0.46920 0.65020 0.25440 1.00000 0.02026 O92 0.87590 0.30950 0.92000 1.00000 0.03293 O93 0.14060 0.68950 0.91750 1.00000 0.02026 O94 0.30450 0.81540 0.07930 1.00000 0.01900 O95 0.95960 0.65240 0.50190 1.00000 0.03040 O96 0.11100 0.67050 0.09230 1.00000 0.04306 O97 0.05800 0.54600 0.79510 1.00000 0.41415 O98 0.13200 -0.00600 0.46410 1.00000 0.06586 O99 0.08400 0.52300 0.70410 1.00000 0.03673 O100 0.16000 0.39100 0.76120 1.00000 0.05319 O101 0.58200 0.13100 0.74240 1.00000 0.12665 O102 0.37200 0.04700 0.78070 1.00000 0.12032 O103 0.95500 0.46200 0.29460 1.00000 0.05066 O104 0.91500 0.48300 0.20520 1.00000 0.03420 O105 0.84400 0.60800 0.26130 1.00000 0.05319 O106 0.46700 0.87500 0.24040 1.00000 0.17351 O107 0.38500 0.01300 0.29890 1.00000 0.11652 O108 0.12400 0.98300 0.94610 1.00000 0.06966 O109 0.87100 0.01700 0.96010 1.00000 0.04559 O110 -0.09600 0.41900 0.75010 1.00000 0.04813 O111 0.09900 0.58100 0.24850 1.00000 0.04559 O112 0.87600 0.01100 0.44510 1.00000 0.05699 O113 0.95800 -0.09000 0.51790 1.00000 0.05066 O114 0.97800 0.09200 0.52020 1.00000 0.04559 O115 0.52200 0.96100 0.71830 1.00000 0.07092 O117 0.04300 0.09200 0.02030 1.00000 0.04559 O118 0.46800 0.05100 0.22140 1.00000 0.04813 O119 0.62800 0.99500 0.80080 1.00000 0.07092 O120 0.62900 0.95400 0.28370 1.00000 0.17478