Klyuchevskite
Gorskaya M G, Filatov S K, Rozhdestvenskaya I V, Vergasova L P
Mineralogical Magazine 56 (1992) 411-416
The crystal structure of klyuchevskite, K3Cu3(Fe,Al)O2(SO4)4,
a new mineral from Kamchatka volcanic sublimates
Locality: Tolbachik Main Fracture Eruption, Kamchatka Peninsula, Russia
_database_code_amcsd 0014497
CELL PARAMETERS: 18.6670 4.9400 18.4050 90.000 101.500 90.000
SPACE GROUP: I2
X-RAY WAVELENGTH: 1.541838
Cell Volume: 1663.145
Density (g/cm3): 3.094
MAX. ABS. INTENSITY / VOLUME**2: 18.27444376
RIR: 1.923
RIR based on corundum from Acta Crystallographica A38 (1982) 733-739
2-THETA INTENSITY D-SPACING H K L Multiplicity
6.16 1.79 14.3529 -1 0 1 2
7.54 15.12 11.7270 1 0 1 2
9.67 100.00 9.1461 2 0 0 2
9.81 95.73 9.0178 0 0 2 2
12.33 52.53 7.1764 -2 0 2 2
14.38 3.68 6.1609 -3 0 1 2
14.56 4.02 6.0823 -1 0 3 2
15.11 10.41 5.8635 2 0 2 2
16.25 3.08 5.4557 3 0 1 2
16.41 4.98 5.4008 1 0 3 2
19.41 1.91 4.5731 4 0 0 2
19.69 5.12 4.5089 0 0 4 2
19.94 1.31 4.4523 -4 0 2 2
21.48 3.42 4.1372 2 1 1 2
21.53 2.82 4.1281 1 1 2 2
22.75 4.05 3.9090 3 0 3 2
23.17 3.19 3.8384 3 1 0 2
23.31 1.07 3.8167 0 1 3 2
23.50 30.38 3.7855 4 0 2 2
23.68 9.24 3.7579 2 0 4 2
24.03 1.64 3.7032 -3 1 2 2
24.10 20.75 3.6924 -2 1 3 2
24.18 2.48 3.6810 -1 0 5 2
24.81 1.98 3.5882 -4 0 4 2
25.80 6.66 3.4538 5 0 1 2
26.07 3.65 3.4174 -3 0 5 2
26.12 7.20 3.4122 1 0 5 2
26.35 14.18 3.3821 3 1 2 2
26.42 4.29 3.3738 2 1 3 2
26.49 3.92 3.3649 -1 1 4 2
27.74 2.78 3.2157 4 1 1 2
28.50 30.73 3.1317 -4 1 3 2
28.59 2.65 3.1226 -3 1 4 2
28.99 6.00 3.0805 -6 0 2 2
29.29 1.59 3.0487 6 0 0 2
29.37 2.36 3.0411 -2 0 6 2
29.72 1.59 3.0059 0 0 6 2
30.40 1.22 2.9400 5 1 0 2
30.43 4.32 2.9373 -5 1 2 2
30.67 12.12 2.9148 -2 1 5 2
31.16 1.13 2.8706 -5 0 5 2
32.21 8.61 2.7790 -4 0 6 2
32.40 5.39 2.7632 4 1 3 2
32.48 13.30 2.7569 3 1 4 2
33.54 17.57 2.6719 5 1 2 2
33.71 16.72 2.6586 -4 1 5 2
33.76 13.86 2.6549 2 1 5 2
34.07 10.50 2.6317 -6 1 1 2
34.16 2.94 2.6246 -1 0 7 2
34.43 3.89 2.6048 -1 1 6 2
35.28 7.34 2.5443 -6 1 3 2
35.55 4.45 2.5254 -3 1 6 2
35.79 10.23 2.5087 6 1 1 2
36.37 28.43 2.4700 0 2 0 1
37.76 1.84 2.3823 0 2 2 2
38.38 2.59 2.3454 5 0 5 2
38.52 1.44 2.3373 -5 0 7 2
38.55 3.22 2.3355 -2 2 2 2
38.82 1.48 2.3200 6 0 4 2
39.17 9.89 2.2999 5 1 4 2
39.18 5.78 2.2992 -6 1 5 2
39.28 1.83 2.2935 -5 1 6 2
39.44 2.19 2.2845 0 1 7 2
40.14 1.85 2.2462 1 2 3 2
40.28 1.31 2.2389 7 0 3 2
40.63 6.36 2.2208 -7 1 4 2
40.64 2.84 2.2199 3 0 7 2
40.92 8.48 2.2054 -4 1 7 2
42.06 10.55 2.1485 7 1 2 2
43.49 1.04 2.0810 -8 1 3 2
43.50 1.57 2.0804 -1 1 8 2
43.76 3.25 2.0686 4 2 2 2
43.82 1.12 2.0660 -9 0 1 2
43.86 2.65 2.0641 2 2 4 2
43.95 1.56 2.0601 -3 1 8 2
44.70 2.86 2.0274 -3 0 9 2
45.13 1.30 2.0091 5 2 1 2
45.20 4.27 2.0063 -6 1 7 2
45.92 1.33 1.9763 9 0 1 2
46.37 4.16 1.9583 -8 1 5 2
46.54 1.34 1.9513 5 1 6 2
46.57 1.71 1.9504 1 0 9 2
47.16 1.39 1.9270 -6 2 2 2
47.27 3.01 1.9229 7 1 4 2
47.37 1.20 1.9192 6 2 0 2
47.42 3.47 1.9173 -2 2 6 2
47.56 2.00 1.9118 -9 1 2 2
47.65 2.11 1.9084 0 2 6 2
48.55 2.55 1.8751 5 2 3 2
49.21 1.26 1.8516 -6 2 4 2
49.80 1.86 1.8309 6 2 2 2
50.76 3.09 1.7987 -1 2 7 2
51.65 1.08 1.7697 -7 0 9 2
52.23 1.44 1.7514 1 2 7 2
52.77 1.60 1.7347 -6 1 9 2
53.37 2.95 1.7167 -1 1 10 2
54.39 1.45 1.6869 -11 0 1 2
54.54 1.02 1.6824 -2 2 8 2
54.70 1.26 1.6779 8 2 0 2
54.79 1.30 1.6754 -10 1 5 2
54.80 1.70 1.6753 7 0 7 2
54.89 1.25 1.6726 8 1 5 2
55.67 3.33 1.6511 3 2 7 2
56.20 1.11 1.6367 9 0 5 2
57.42 1.00 1.6048 -11 1 2 2
58.22 1.67 1.5847 -9 2 1 2
58.44 2.51 1.5791 -9 2 3 2
58.52 1.91 1.5772 -8 0 10 2
58.76 2.56 1.5713 -1 2 9 2
58.83 1.30 1.5697 -10 1 7 2
58.94 1.16 1.5671 -3 2 9 2
59.28 2.41 1.5588 3 1 10 2
59.57 1.21 1.5518 3 3 2 2
59.94 1.19 1.5431 9 2 1 2
60.37 1.26 1.5333 -7 0 11 2
60.48 4.86 1.5307 1 2 9 2
60.72 2.49 1.5254 -4 3 3 2
60.76 1.30 1.5244 12 0 0 2
61.94 1.42 1.4982 -2 3 5 2
63.00 2.44 1.4754 3 3 4 2
63.32 1.38 1.4687 -10 2 4 2
63.59 2.32 1.4632 -3 1 12 2
63.65 2.06 1.4619 5 3 2 2
63.76 1.71 1.4597 -4 3 5 2
63.79 2.20 1.4591 2 3 5 2
63.98 1.85 1.4552 -6 3 1 2
64.00 1.12 1.4549 3 2 9 2
64.74 1.10 1.4399 -6 3 3 2
65.07 1.35 1.4334 6 3 1 2
65.65 1.21 1.4222 -9 0 11 2
67.05 1.28 1.3958 -11 2 3 2
67.20 2.47 1.3930 -11 2 1 2
67.32 1.06 1.3909 5 3 4 2
67.33 1.50 1.3908 -6 3 5 2
67.40 1.77 1.3895 -8 0 12 2
67.56 1.22 1.3865 7 2 7 2
69.34 1.02 1.3552 7 3 2 2
70.89 1.04 1.3293 -8 2 10 2
72.82 1.15 1.2989 -12 0 10 2
72.92 1.07 1.2972 12 2 0 2
77.25 2.18 1.2350 0 4 0 1
78.33 1.18 1.2206 4 1 13 2
83.04 1.03 1.1630 3 3 10 2
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XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs
For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.