data_global
_chemical_name_mineral 'Ralphcannonite'
loop_
_publ_author_name
'Bindi L'
'Biagioni C'
'Raber T'
'Roth T'
'Nestola F'
_journal_name_full 'Mineralogical Magazine'
_journal_volume 79 
_journal_year 2015
_journal_page_first 1089
_journal_page_last 1098
_publ_section_title
;
 Ralphcannonite, AgZn2TlAs2S6, a new mineral of the routhierite isotypic
 series from Lengenbach, Binn Valley, Switzerland
;
_database_code_amcsd 0020618
_chemical_compound_source 'Lengenbach quarry, Binn Valley, Wallis, Switzerland'
_chemical_formula_sum 'Ag.634 Zn1.331 Fe.468 Hg.318 Cu.249 Tl (As1.99 Sb.01) S6'
_cell_length_a 9.861
_cell_length_b 9.861
_cell_length_c 11.125
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1081.787
_exptl_crystal_density_diffrn      4.963
_symmetry_space_group_name_H-M 'I -4 2 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  '-y,-x,z'
  '1/2-y,1/2-x,1/2+z'
  'y,-x,-z'
  '1/2+y,1/2-x,1/2-z'
  '-x,y,-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,z'
  '1/2-x,1/2-y,1/2+z'
  'y,x,z'
  '1/2+y,1/2+x,1/2+z'
  '-y,x,-z'
  '1/2-y,1/2+x,1/2-z'
  'x,-y,-z'
  '1/2+x,1/2-y,1/2-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
AgM2   0.22280   0.50000   0.50000   0.31700   0.04050
ZnM2   0.22280   0.50000   0.50000   0.29000   0.04050
FeM2   0.22280   0.50000   0.50000   0.23400   0.04050
HgM2   0.22280   0.50000   0.50000   0.15900   0.04050
ZnM1   0.00000   0.50000   0.25000   0.75100   0.03340
CuM1   0.00000   0.50000   0.25000   0.24900   0.03340
Tl   0.00000   0.00000   0.35240   1.00000   0.04130
As   0.26110   0.26110   0.25870   0.99500   0.04000
Sb   0.26110   0.26110   0.25870   0.00500   0.04000
S1   0.09430   0.33080   0.37430   1.00000   0.03700
S2   0.12570   0.12570   0.12950   1.00000   0.04000