data_global
_amcsd_formula_title 'Al F5 Tl2'
loop_
_publ_author_name
'Brosset C'
_journal_name_full 'Zeitschrift fur Anorganische und Allgemeine Chemie'
_journal_volume 235 
_journal_year 1937
_journal_page_first 139
_journal_page_last 147
_publ_section_title
;
 Herstellung und Kristallbau der Verbindungen Tl Al F4 und Tl2 Al F5
 _cod_database_code 1010159
;
_database_code_amcsd 0017089
_chemical_formula_sum 'Tl2 Al F5'
_cell_length_a 10.06
_cell_length_b 8.24
_cell_length_c 7.46
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 618.392
_exptl_crystal_density_diffrn      5.701
_symmetry_space_group_name_H-M 'C 2 2 21'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  'x,-y,-z'
  '1/2+x,1/2-y,-z'
  '-x,-y,1/2+z'
  '1/2-x,1/2-y,1/2+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Tl1   0.29000   0.20000   0.00000
Al1   0.00000   0.00000   0.25000
F1   0.00000   0.23000   0.25000
F2   0.00000   0.77000   0.25000
F3   0.03300   0.00000   0.00000
F4   0.19000   0.00000   0.29000