Bottinoite Bonazzi P, Mazzi F American Mineralogist 81 (1996) 1494-1500 Bottinoite, Ni(H2O)6[Sb(OH)6]2: Crystal structure, twinning and hydrogen-bond model Sample: BN1, natural Locality: Bottino mine, Apuan Alps, Italy Note: U(1,2) for Sb5 and Sb6 changed to match symmetry constraints. _database_code_amcsd 0001842 16.045 16.045 9.784 90 90 120 P3 atom x y z U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) Sb1 0 0 0 .016 .016 .005 .008 0 0 Sb2 2/3 1/3 -.0888 .008 .008 .002 .004 0 0 Sb3 1/3 2/3 .0002 .004 .004 .065 .002 0 0 Sb4 0 0 .4943 .012 .012 .011 .006 0 0 Sb5 2/3 1/3 .4193 .015 .015 .011 .0075 0 0 Sb6 1/3 2/3 .5037 .003 .003 .019 .0015 0 0 Sb7 .3273 -.0066 .4706 .012 .007 .020 .003 .003 .002 Sb8 .6679 .0052 .4501 .014 .005 .003 .000 .002 .001 Ni1 .3372 .0100 -.0368 .009 .007 .036 .002 .004 -.001 Ni2 .6605 -.0066 -.0524 .020 .036 .002 .016 .006 .002 O1 .033 .118 -.118 .036 .003 .041 .009 -.015 -.006 O2 .114 .084 .109 .040 .037 .006 .019 .008 -.004 O3 .581 .221 -.202 .016 .010 .036 -.007 -.013 -.007 O4 .701 .257 .023 .019 .015 .007 .006 .000 .000 O5 .302 .554 .118 .019 .016 .007 .006 .005 .003 O6 .360 .779 -.111 .025 .012 .021 .017 -.001 -.001 O7 .316 .099 -.158 .106 .029 .032 .054 .039 .015 O8 .425 .114 .099 .046 .024 .007 .024 .000 -.004 O9 .452 .034 -.152 .024 .008 .040 .005 .023 .009 O10 .365 -.085 .083 .015 .015 .033 .001 -.013 .003 O11 .254 -.108 -.160 .008 .004 .054 -.003 -.010 -.002 O12 .216 -.025 .088 .011 .023 .039 .010 -.006 -.013 O13 .580 .023 .068 .022 .057 .009 .021 .011 .008 O14 .697 .110 -.165 .009 .014 .019 .004 -.005 .004 O15 .778 .080 .067 .016 .029 .016 .005 .010 .019 O16 .755 -.026 -.175 .015 .054 .048 .026 .009 .034 O17 .631 -.128 .006 .012 .026 .010 .008 -.002 -.002 O18 .551 -.092 -.169 .018 .036 .012 .008 -.008 -.002 O19 .057 .109 .368 .025 .007 .037 .008 .011 .009 O20 .116 .041 .610 .020 .020 .020 .012 .014 -.002 O21 .550 .264 .537 .007 .007 .006 .000 .001 .004 O22 .620 .221 .299 .023 .027 .009 .018 -.008 -.015 O23 .261 .550 .613 .016 .007 .012 .005 .001 -.006 O24 .393 .779 .379 .016 .024 .044 .018 .001 .008 O25 .260 .038 .343 .026 .020 .018 .018 -.008 .006 O26 .375 .119 .575 .010 .014 .007 .007 .003 -.004 O27 .446 .058 .341 .008 .029 .017 .009 .006 -.003 O28 .399 -.052 .582 .014 .013 .011 .013 -.005 -.007 O29 .280 -.123 .348 .023 .008 .024 .004 .005 .003 O30 .214 -.070 .582 .009 .008 .021 .000 .006 .005 O31 .619 .072 .568 .009 .020 .008 .009 -.001 .008 O32 .736 .117 .326 .026 .031 .019 .011 -.008 .005 O33 .783 .057 .557 .031 .014 .007 .009 -.005 .003 O34 .710 -.062 .323 .018 .013 .007 .028 .001 -.002 O35 .608 -.106 .563 .017 .013 .007 .003 .001 .002 O36 .550 -.042 .333 .013 .016 .015 .003 .001 .001