Krupkaite Topa D, Makovicky E, Balic-Zunic T The Canadian Mineralogist 40 (2002) 1147-1159 The structural role of excess Cu and Pb in gladite and krupkaite based on new refinements of their structure Sample: bd47 _database_code_amcsd 0005782 CELL PARAMETERS: 4.0134 11.2080 11.5600 90.000 90.000 90.000 SPACE GROUP: Pmc2_1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 519.994 Density (g/cm3): 6.953 MAX. ABS. INTENSITY / VOLUME**2: 78.10406013 RIR: 3.658 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 7.89 1.77 11.2080 0 1 0 2 11.00 2.86 8.0468 0 1 1 2 15.33 12.68 5.7800 0 0 2 1 15.81 1.84 5.6040 0 2 0 2 17.26 19.19 5.1371 0 1 2 2 22.09 52.65 4.0234 0 2 2 2 22.15 1.06 4.0134 1 0 0 2 23.55 24.84 3.7785 1 1 0 4 23.82 10.67 3.7360 0 3 0 2 24.43 100.00 3.6440 0 1 3 2 24.79 52.38 3.5915 1 1 1 4 25.05 84.68 3.5550 0 3 1 2 27.05 20.89 3.2966 1 0 2 2 28.10 11.41 3.1752 0 2 3 2 28.22 62.58 3.1626 1 1 2 4 28.42 89.78 3.1402 1 2 1 4 28.45 6.13 3.1376 0 3 2 2 30.94 4.57 2.8900 0 0 4 1 31.48 90.01 2.8414 1 2 2 4 31.94 4.45 2.8020 0 4 0 2 31.98 2.63 2.7985 0 1 4 2 32.75 17.35 2.7346 1 3 0 4 32.89 4.30 2.7231 0 4 1 2 33.41 2.56 2.6823 0 3 3 2 33.68 38.46 2.6611 1 3 1 4 34.93 46.92 2.5686 0 2 4 2 35.61 16.18 2.5214 0 4 2 2 36.07 21.02 2.4901 1 2 3 4 36.34 4.46 2.4719 1 3 2 4 38.38 26.51 2.3452 1 0 4 2 39.25 26.02 2.2955 1 1 4 4 39.42 2.79 2.2859 0 3 4 2 39.78 5.57 2.2662 0 4 3 2 39.81 1.05 2.2643 0 1 5 2 40.01 23.38 2.2534 1 4 1 4 40.45 6.94 2.2301 1 3 3 4 41.01 3.22 2.2006 0 5 1 2 41.75 10.44 2.1634 1 2 4 4 42.29 7.69 2.1373 0 2 5 2 42.33 20.34 2.1350 1 4 2 4 43.29 4.22 2.0899 0 5 2 2 45.07 3.27 2.0117 0 4 4 2 45.18 34.88 2.0067 2 0 0 2 45.67 1.57 1.9863 1 3 4 4 45.99 33.39 1.9733 1 4 3 4 46.02 9.43 1.9721 1 1 5 4 46.17 10.84 1.9660 0 3 5 2 46.40 13.39 1.9570 1 5 0 4 46.89 22.47 1.9376 0 5 3 2 47.10 4.16 1.9296 1 5 1 4 47.17 10.06 1.9267 0 0 6 1 47.91 1.64 1.8988 0 1 6 2 47.99 1.26 1.8957 2 0 2 2 48.24 9.56 1.8864 1 2 5 4 48.72 1.89 1.8692 2 1 2 4 48.75 7.85 1.8680 0 6 0 2 49.15 4.53 1.8537 1 5 2 4 49.42 2.57 1.8441 0 6 1 2 50.06 2.62 1.8220 0 2 6 2 50.77 1.53 1.7984 1 4 4 4 50.85 9.02 1.7957 2 2 2 4 51.41 2.65 1.7775 0 6 2 2 51.60 3.17 1.7712 0 5 4 2 51.71 1.89 1.7678 2 3 0 4 51.78 11.77 1.7655 1 3 5 4 52.03 19.26 1.7578 2 1 3 4 52.35 17.65 1.7475 2 3 1 4 52.44 4.69 1.7449 1 5 3 4 52.70 9.76 1.7369 1 0 6 2 53.38 5.20 1.7164 1 1 6 4 53.51 1.93 1.7124 0 3 6 2 54.06 2.54 1.6963 2 2 3 4 54.16 1.23 1.6935 1 6 0 4 54.26 1.39 1.6905 2 3 2 4 54.78 4.82 1.6757 1 6 1 4 55.38 2.38 1.6590 1 2 6 4 55.77 1.29 1.6483 2 0 4 2 56.40 1.22 1.6315 2 4 0 4 56.47 4.90 1.6297 1 4 5 4 57.01 1.39 1.6155 2 4 1 4 58.10 1.36 1.5876 0 4 6 2 58.17 2.35 1.5860 0 7 1 2 58.24 1.06 1.5841 0 2 7 2 58.35 15.00 1.5813 2 2 4 4 58.61 2.67 1.5750 1 3 6 4 58.81 5.23 1.5701 2 4 2 4 58.87 2.75 1.5688 0 6 4 2 59.95 2.70 1.5430 0 7 2 2 61.26 8.38 1.5132 1 1 7 4 61.38 5.67 1.5104 0 3 7 2 61.49 1.07 1.5081 2 3 4 4 61.75 2.23 1.5024 2 4 3 4 62.14 1.68 1.4937 1 5 5 4 62.65 1.43 1.4828 2 5 1 4 63.02 2.38 1.4750 1 7 1 4 63.09 2.65 1.4735 1 2 7 4 63.60 3.31 1.4629 2 2 5 4 63.69 4.16 1.4611 1 6 4 4 63.69 1.48 1.4611 0 5 6 2 64.36 1.85 1.4475 2 5 2 4 64.72 7.38 1.4403 1 7 2 4 65.08 1.45 1.4331 0 1 8 2 65.62 2.68 1.4227 0 4 7 2 65.73 1.54 1.4207 2 4 4 4 66.59 5.34 1.4043 2 3 5 4 66.87 1.13 1.3992 0 2 8 2 67.16 10.93 1.3939 2 5 3 4 67.38 5.07 1.3898 2 0 6 2 67.51 3.21 1.3874 1 7 3 4 68.32 3.27 1.3730 1 5 6 4 68.64 4.07 1.3673 2 6 0 4 68.70 2.07 1.3662 1 6 5 4 68.97 1.70 1.3616 0 8 2 2 69.19 1.40 1.3578 2 6 1 4 69.71 1.28 1.3489 2 2 6 4 70.17 2.54 1.3411 0 6 6 2 70.19 1.10 1.3410 1 4 7 4 70.82 1.51 1.3306 2 6 2 4 70.98 1.78 1.3279 2 5 4 4 71.30 1.04 1.3227 1 8 0 4 71.32 7.36 1.3224 1 7 4 4 71.39 4.12 1.3212 1 2 8 4 71.49 1.50 1.3197 3 1 1 4 71.84 1.82 1.3141 1 8 1 4 72.58 1.16 1.3026 2 3 6 4 73.09 2.34 1.2946 3 1 2 4 73.20 3.29 1.2931 3 2 1 4 74.33 2.26 1.2761 0 1 9 2 74.61 1.46 1.2720 1 6 6 4 74.79 3.68 1.2695 3 2 2 4 75.30 4.21 1.2621 1 5 7 4 75.40 1.37 1.2607 0 8 4 2 76.01 1.70 1.2521 3 3 1 4 76.57 1.43 1.2443 2 7 1 4 77.02 1.43 1.2382 0 9 1 2 77.18 1.84 1.2359 2 6 4 4 77.41 1.25 1.2328 3 2 3 4 78.14 1.83 1.2232 2 7 2 4 78.14 2.61 1.2232 1 4 8 4 78.84 1.71 1.2140 3 0 4 2 79.39 1.90 1.2070 3 1 4 4 79.41 3.92 1.2068 2 3 7 4 79.89 1.73 1.2007 3 4 1 4 80.81 1.55 1.1894 1 9 0 4 81.32 1.02 1.1831 1 9 1 4 81.39 1.14 1.1823 1 6 7 4 81.44 1.50 1.1818 3 4 2 4 81.49 1.07 1.1812 2 5 6 4 82.64 1.26 1.1676 0 4 9 2 82.76 1.07 1.1663 2 1 8 4 83.07 1.29 1.1626 1 3 9 4 83.09 1.40 1.1625 1 5 8 4 83.25 2.09 1.1606 2 4 7 4 84.01 3.21 1.1520 3 4 3 4 84.30 1.27 1.1488 3 5 0 4 86.35 1.35 1.1267 2 8 2 4 86.89 1.39 1.1211 1 4 9 4 87.48 2.09 1.1150 2 6 6 4 87.89 2.27 1.1108 1 0 10 2 88.38 1.39 1.1060 3 3 5 4 89.10 1.22 1.0989 3 0 6 2 89.36 1.11 1.0964 0 9 5 2 89.98 2.02 1.0905 1 8 6 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.