Manganilvaite Zotov N, Kockelmann W, Jacobsen S D, Mitov I, Paneva D, Vassileva R D, Bonev I K The Canadian Mineralogist 43 (2005) 1043-1053 Structure and cation order in manganilvaite: a combined X-ray-diffraction, neutron-diffraction and mossbauer study Sample: Ossikovo Pb-Zn skarn, Rhodope Mountains, Bulgaria Sample: single crystal X-ray analysis _database_code_amcsd 0006025 CELL PARAMETERS: 13.0150 8.8430 5.8396 90.000 90.110 90.000 SPACE GROUP: P2_1/a X-RAY WAVELENGTH: 1.541838 Cell Volume: 672.088 Density (g/cm3): 3.483 MAX. ABS. INTENSITY / VOLUME**2: 8.372391920 RIR: 0.783 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 12.10 2.49 7.3144 1 1 0 4 13.61 21.34 6.5075 2 0 0 2 15.17 22.92 5.8396 0 0 1 2 16.92 4.87 5.2413 2 1 0 4 18.21 12.51 4.8730 0 1 1 4 19.46 40.67 4.5612 1 1 1 4 20.08 20.66 4.4215 0 2 0 2 22.82 9.92 3.8976 2 1 1 4 22.83 6.24 3.8949 3 1 0 4 24.34 1.30 3.6572 2 2 0 4 25.27 8.38 3.5250 0 2 1 4 26.18 1.00 3.4035 -1 2 1 4 26.20 12.03 3.4015 1 2 1 4 27.41 6.71 3.2537 4 0 0 2 27.55 15.35 3.2377 3 1 1 4 28.83 2.15 3.0966 3 2 0 4 30.62 38.00 2.9198 0 0 2 2 31.11 31.39 2.8749 1 3 0 4 31.45 100.00 2.8446 -4 0 1 2 31.50 39.87 2.8400 4 0 1 2 32.72 5.18 2.7373 -3 2 1 4 32.75 25.12 2.7342 3 2 1 4 33.02 29.36 2.7127 -1 1 2 4 33.05 32.51 2.7107 1 1 2 4 33.37 46.41 2.6851 2 3 0 4 34.07 1.46 2.6314 0 3 1 4 34.22 4.04 2.6206 4 2 0 4 34.78 10.95 2.5797 -1 3 1 4 34.79 1.37 2.5788 1 3 1 4 35.16 8.61 2.5524 -2 1 2 4 35.21 8.14 2.5490 2 1 2 4 36.83 44.42 2.4403 -2 3 1 4 36.86 9.68 2.4388 2 3 1 4 36.87 2.74 2.4381 3 3 0 4 36.89 6.67 2.4365 0 2 2 4 37.60 8.88 2.3923 -4 2 1 4 37.64 39.19 2.3895 4 2 1 4 38.50 12.32 2.3382 -3 1 2 4 38.57 10.92 2.3343 3 1 2 4 39.27 7.50 2.2944 5 1 1 4 40.06 4.00 2.2508 -3 3 1 4 41.33 2.58 2.1845 4 3 0 4 41.43 12.66 2.1795 1 4 0 4 41.52 9.92 2.1752 -4 0 2 2 41.60 8.83 2.1710 4 0 2 2 42.53 1.65 2.1258 -3 2 2 4 42.59 2.07 2.1229 3 2 2 4 42.81 32.57 2.1122 -4 1 2 4 42.89 32.98 2.1084 4 1 2 4 43.22 17.22 2.0933 2 4 0 4 43.23 1.75 2.0928 5 2 1 4 44.20 1.82 2.0490 -1 3 2 4 44.22 1.63 2.0481 1 3 2 4 44.37 2.45 2.0417 1 4 1 4 44.53 1.78 2.0347 -6 0 1 2 45.82 1.84 1.9805 6 1 1 4 45.90 3.67 1.9772 -2 3 2 4 45.94 4.13 1.9756 2 3 2 4 46.05 6.66 1.9709 -2 4 1 4 46.07 7.36 1.9701 2 4 1 4 46.08 5.29 1.9697 3 4 0 4 46.53 2.59 1.9518 -4 2 2 4 46.61 2.43 1.9488 4 2 2 4 46.66 1.22 1.9465 0 0 3 2 47.85 3.99 1.9010 0 1 3 4 47.89 6.19 1.8994 -5 1 2 4 47.98 6.86 1.8960 5 1 2 4 48.37 3.63 1.8816 -1 1 3 4 48.81 3.79 1.8659 3 4 1 4 49.22 6.58 1.8514 -5 3 1 4 49.26 1.03 1.8498 5 3 1 4 49.36 4.06 1.8465 6 2 1 4 49.87 1.69 1.8286 4 4 0 4 49.96 1.20 1.8257 -2 1 3 4 50.14 1.82 1.8195 7 1 0 4 51.28 1.20 1.7815 0 2 3 4 51.78 2.33 1.7655 -1 2 3 4 51.88 1.52 1.7625 0 4 2 4 52.37 3.51 1.7471 6 3 0 4 52.38 3.90 1.7469 -1 4 2 4 52.39 3.15 1.7463 1 4 2 4 52.42 1.77 1.7456 -4 4 1 4 52.52 2.85 1.7424 -3 1 3 4 53.46 15.43 1.7139 7 2 0 4 53.88 1.21 1.7017 -2 4 2 4 54.19 1.55 1.6927 0 5 1 4 54.82 14.41 1.6745 -6 3 1 4 54.87 5.01 1.6731 6 3 1 4 54.92 4.46 1.6718 -4 0 3 2 55.02 12.19 1.6690 4 0 3 2 55.74 2.64 1.6490 -3 2 3 4 56.14 4.06 1.6384 -2 5 1 4 56.15 17.05 1.6379 2 5 1 4 56.32 3.21 1.6336 -3 4 2 4 56.37 3.31 1.6323 3 4 2 4 56.57 7.56 1.6269 8 0 0 2 56.71 8.55 1.6233 -5 3 2 4 56.79 8.61 1.6212 5 3 2 4 57.16 3.74 1.6115 1 3 3 4 58.55 2.70 1.5766 -2 3 3 4 58.60 10.53 1.5754 2 3 3 4 59.07 6.67 1.5638 -4 2 3 4 59.17 1.37 1.5615 4 2 3 4 59.72 2.66 1.5483 6 4 0 4 59.98 1.84 1.5424 8 1 1 4 60.23 1.76 1.5366 -5 1 3 4 60.65 18.24 1.5268 8 2 0 4 61.84 17.08 1.5002 -6 3 2 4 61.94 16.59 1.4982 6 3 2 4 63.08 1.53 1.4738 0 6 0 2 63.08 19.93 1.4738 -2 5 2 4 63.11 19.67 1.4731 2 5 2 4 63.53 3.08 1.4645 1 6 0 4 63.75 28.55 1.4599 0 0 4 2 65.31 1.21 1.4288 -3 5 2 4 65.35 1.19 1.4279 3 5 2 4 65.39 4.00 1.4272 9 1 0 4 65.46 1.13 1.4259 -2 4 3 4 65.61 1.43 1.4229 7 4 0 4 65.64 4.24 1.4223 -8 0 2 2 65.73 1.32 1.4206 -1 6 1 4 65.76 3.90 1.4200 8 0 2 2 67.07 1.92 1.3955 3 6 0 4 67.54 1.94 1.3870 -9 1 1 4 67.64 1.55 1.3851 -3 4 3 4 68.09 2.69 1.3770 5 3 3 4 68.45 7.53 1.3707 6 5 0 4 69.21 4.10 1.3575 -3 6 1 4 70.60 4.01 1.3341 6 5 1 4 71.74 1.00 1.3157 0 6 2 4 72.62 1.87 1.3019 -1 3 4 4 72.65 2.23 1.3015 1 3 4 4 72.67 1.86 1.3012 -6 3 3 4 72.79 5.32 1.2992 6 3 3 4 73.56 2.03 1.2876 10 1 0 4 73.82 7.76 1.2836 -2 5 3 4 73.86 3.88 1.2830 -2 3 4 4 73.87 2.11 1.2830 2 5 3 4 73.92 3.97 1.2821 2 3 4 4 74.11 1.12 1.2793 8 3 2 4 74.76 1.69 1.2698 10 0 1 2 74.96 1.98 1.2669 9 3 1 4 75.95 2.23 1.2529 -5 6 1 4 75.98 1.34 1.2524 5 6 1 4 76.26 4.01 1.2485 10 2 0 4 76.78 1.43 1.2414 -6 5 2 4 76.87 1.48 1.2402 6 5 2 4 77.09 1.19 1.2372 -8 1 3 4 78.45 1.66 1.2191 6 6 0 4 80.12 1.28 1.1978 -2 4 4 4 80.18 1.28 1.1971 2 4 4 4 81.00 2.67 1.1871 -9 3 2 4 81.12 2.68 1.1855 9 3 2 4 81.78 1.79 1.1776 4 7 0 4 82.69 1.33 1.1670 -10 3 1 4 82.76 2.71 1.1662 10 3 1 4 84.20 1.07 1.1499 9 1 3 4 85.68 2.56 1.1338 3 6 3 4 86.86 2.90 1.1214 -6 5 3 4 87.75 2.53 1.1123 -7 2 4 4 87.94 2.59 1.1104 7 2 4 4 88.44 1.02 1.1054 0 8 0 2 88.67 1.62 1.1031 -10 3 2 4 88.80 1.48 1.1018 10 3 2 4 89.00 4.37 1.0999 -4 0 5 2 89.13 1.93 1.0986 4 0 5 2 89.79 1.27 1.0923 3 2 5 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.