Parawulffite Pekov I V, Zubkova N V, Yapaskurt V O, Belakovskiy D I, Chukanov N V, Lykova I S, Savelyev D P, Sidorov E G, Pushcharovsky D Y The Canadian Mineralogist 52 (2014) 699-716 Wulffite, K3NaCu4O2(SO4)4, and parawulffite, K5Na3Cu8O4(SO4)8, two new minerals from fumarole sublimates of the Tolbachik volcano, Kamchatka, Russia Locality: Tolbachik volcano, Kamchatka, Russia _database_code_amcsd 0020468 CELL PARAMETERS: 13.9043 4.9765 23.5855 90.000 90.209 90.000 SPACE GROUP: P2/c X-RAY WAVELENGTH: 1.541838 Cell Volume: 1631.982 Density (g/cm3): 3.324 MAX. ABS. INTENSITY / VOLUME**2: 16.36732929 RIR: 1.603 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 7.50 4.34 11.7927 0 0 2 2 9.82 100.00 9.0098 -1 0 2 2 9.85 97.58 8.9774 1 0 2 2 12.73 47.64 6.9521 2 0 0 2 15.03 22.49 5.8963 0 0 4 2 19.71 5.15 4.5049 -2 0 4 2 19.78 8.51 4.4887 2 0 4 2 20.62 2.47 4.3082 3 0 2 2 21.13 2.77 4.2049 0 1 3 4 22.10 1.60 4.0227 1 1 3 4 22.28 1.07 3.9897 -2 1 1 4 23.50 13.33 3.7862 -1 0 6 2 24.38 6.09 3.6503 -3 0 4 2 24.47 5.19 3.6374 3 0 4 2 24.72 1.15 3.6011 -2 1 3 4 25.63 11.45 3.4761 4 0 0 2 26.00 3.10 3.4271 -2 0 6 2 26.03 8.75 3.4235 0 1 5 4 26.28 2.80 3.3916 3 1 0 4 26.54 3.33 3.3584 -3 1 1 4 26.69 1.09 3.3398 -2 1 4 4 26.71 1.10 3.3375 -4 0 2 2 26.76 6.74 3.3309 4 0 2 2 26.80 4.21 3.3263 -1 1 5 4 28.69 48.38 3.1112 3 1 3 4 29.04 45.59 3.0745 -2 1 5 4 29.75 1.26 3.0033 -3 0 6 2 29.79 2.38 2.9992 -4 0 4 2 29.86 2.27 2.9925 3 0 6 2 30.32 1.15 2.9482 0 0 8 2 30.37 2.72 2.9434 -3 1 4 4 30.98 1.56 2.8862 -1 0 8 2 31.03 3.31 2.8819 1 0 8 2 31.61 10.48 2.8301 -4 1 1 4 31.64 8.05 2.8281 4 1 1 4 32.47 2.29 2.7572 -3 1 5 4 32.56 1.72 2.7502 3 1 5 4 32.72 36.16 2.7371 -1 1 7 4 32.76 23.10 2.7339 1 1 7 4 32.96 2.42 2.7178 -2 0 8 2 33.05 3.26 2.7106 2 0 8 2 33.07 9.80 2.7088 -5 0 2 2 33.12 3.94 2.7044 5 0 2 2 33.41 10.45 2.6817 -4 1 3 4 33.48 22.00 2.6766 4 1 3 4 34.61 2.30 2.5920 -2 1 7 4 35.97 1.93 2.4967 -1 1 8 4 36.10 37.29 2.4883 0 2 0 2 36.90 7.55 2.4359 4 1 5 4 37.22 4.31 2.4156 -5 1 1 4 37.25 8.93 2.4140 5 1 1 4 37.50 1.43 2.3985 -1 2 2 4 37.51 1.54 2.3979 1 2 2 4 37.58 5.49 2.3935 -3 1 7 4 38.16 1.08 2.3585 0 0 10 2 38.42 2.39 2.3427 2 2 0 4 38.70 1.24 2.3267 -1 0 10 2 38.75 3.34 2.3239 1 0 10 2 38.79 1.11 2.3216 -5 1 3 4 38.84 12.43 2.3187 0 1 9 4 38.86 16.60 2.3174 5 1 3 4 38.98 1.96 2.3105 -4 1 6 4 39.10 1.52 2.3039 4 1 6 4 39.30 2.71 2.2925 0 2 4 4 40.43 1.53 2.2310 2 0 10 2 40.99 16.47 2.2018 -2 1 9 4 41.83 1.33 2.1595 -6 0 4 2 41.90 1.05 2.1560 -3 2 2 4 41.91 2.89 2.1557 5 1 5 4 43.10 1.01 2.0989 3 0 10 2 43.22 1.14 2.0931 -6 1 1 4 43.25 3.97 2.0919 6 1 1 4 43.71 2.83 2.0710 3 1 9 4 44.10 2.27 2.0537 3 2 4 4 44.98 1.18 2.0155 4 2 1 4 45.51 1.13 1.9931 6 0 6 2 46.01 3.41 1.9726 -5 1 7 4 46.33 10.18 1.9599 -7 0 2 2 46.70 6.38 1.9451 1 0 12 2 47.28 2.79 1.9224 2 2 7 4 47.43 3.62 1.9167 6 1 5 4 47.45 2.38 1.9161 -3 2 6 4 47.48 1.09 1.9150 -4 2 4 4 47.52 1.59 1.9132 3 2 6 4 47.98 1.34 1.8963 -2 1 11 4 48.16 1.02 1.8895 2 0 12 2 48.33 2.74 1.8834 1 2 8 4 49.74 3.33 1.8330 2 2 8 4 49.76 5.82 1.8325 -5 2 2 4 49.97 3.43 1.8251 -6 0 8 2 50.28 2.83 1.8145 -3 1 11 4 50.50 1.28 1.8071 3 0 12 2 51.47 1.11 1.7754 -7 0 6 2 53.65 1.60 1.7082 4 0 12 2 53.99 1.87 1.6984 1 2 10 4 54.68 3.58 1.6786 -5 2 6 4 54.87 1.11 1.6732 -1 0 14 2 55.11 1.09 1.6666 4 2 8 4 55.15 1.99 1.6655 8 0 4 2 55.30 2.96 1.6611 2 2 10 4 56.01 1.80 1.6418 -6 1 9 4 56.13 2.51 1.6387 -2 0 14 2 56.42 4.45 1.6309 -6 2 4 4 57.44 3.93 1.6044 3 2 10 4 57.66 1.08 1.5988 -2 3 2 4 59.16 1.21 1.5618 3 3 0 4 59.29 1.22 1.5586 -6 2 6 4 59.73 1.31 1.5481 8 1 5 4 60.09 5.54 1.5396 -7 2 2 4 60.34 2.06 1.5340 4 2 10 4 60.41 3.68 1.5324 1 2 12 4 60.45 4.49 1.5315 3 3 3 4 60.46 2.30 1.5311 9 0 2 2 60.64 3.23 1.5271 -2 3 5 4 61.03 2.58 1.5182 -4 0 14 2 61.39 1.07 1.5102 -3 3 4 4 61.63 1.43 1.5048 2 2 12 4 62.09 2.06 1.4948 8 0 8 2 62.12 1.15 1.4942 -4 3 1 4 62.13 1.19 1.4939 4 3 1 4 62.78 3.29 1.4800 -1 3 7 4 62.81 2.46 1.4795 1 3 7 4 63.18 2.71 1.4717 -6 2 8 4 63.25 1.63 1.4702 4 3 3 4 63.43 1.86 1.4664 -1 0 16 2 63.64 2.72 1.4622 3 2 12 4 64.47 2.20 1.4453 -7 2 6 4 64.94 1.15 1.4361 9 0 6 2 65.35 1.00 1.4280 -3 1 15 4 65.44 1.73 1.4263 4 3 5 4 65.89 1.67 1.4176 -3 3 7 4 66.38 1.40 1.4083 4 2 12 4 66.75 1.87 1.4013 5 3 3 4 66.78 2.14 1.4008 -7 1 11 4 67.21 1.18 1.3929 -8 1 9 4 67.59 1.12 1.3859 -8 2 4 4 68.23 2.00 1.3745 -2 3 9 4 68.44 3.58 1.3708 6 1 13 4 68.57 1.06 1.3685 -2 2 14 4 68.77 1.47 1.3650 -6 0 14 2 69.52 1.09 1.3522 10 0 4 2 69.82 1.06 1.3471 5 2 12 4 70.44 1.49 1.3367 10 1 1 4 70.46 1.37 1.3364 0 1 17 4 72.00 1.48 1.3115 2 1 17 4 72.48 1.08 1.3040 9 2 2 4 73.00 1.47 1.2960 -4 2 14 4 73.44 1.57 1.2894 -10 1 5 4 73.97 1.05 1.2814 8 2 8 4 76.58 2.03 1.2441 0 4 0 2 78.10 1.01 1.2237 -11 1 1 4 78.45 1.14 1.2190 -8 1 13 4 78.58 2.10 1.2175 -9 1 11 4 79.06 1.58 1.2112 -11 1 3 4 80.38 1.15 1.1947 7 1 15 4 83.95 1.04 1.1527 -11 1 7 4 89.33 1.16 1.0966 12 1 5 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.