data_global
_chemical_name_mineral 'Fluoro-edenite'
loop_
_publ_author_name
'Oberti R'
'Hawthorne F C'
'Raudsepp M'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 9 
_journal_year 1997
_journal_page_first 115
_journal_page_last 122
_publ_section_title
;
 The behaviour of Mn in amphiboles: Mn in synthetic
 fluor-edenite and synthetic fluor-pargasite
 Sample: MFE
;
_database_code_amcsd 0006647
_chemical_formula_sum 'Na1.18 Mg4.35 Mn.87 Al1.24 Ca1.41 Si6.92 O22 F2'
_cell_length_a 9.829
_cell_length_b 18.024
_cell_length_c 5.284
_cell_angle_alpha 90
_cell_angle_beta 104.66
_cell_angle_gamma 90
_cell_volume 905.627
_exptl_crystal_density_diffrn      3.135
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
NaA   0.00000   0.50000   0.00000   0.20000   0.03179
NaAm   0.04410   0.50000   0.10240   0.20000   0.02951
NaA2   0.00000   0.47340   0.00000   0.20000   0.03217
MgM1   0.00000   0.08881   0.50000   0.92500   0.00722
MnM1   0.00000   0.08881   0.50000   0.07500   0.00722
AlM2   0.00000   0.17688   0.00000   0.08000   0.00836
MgM2   0.00000   0.17688   0.00000   0.76000   0.00836
MnM2   0.00000   0.17688   0.00000   0.16000   0.00836
MgM3   0.00000   0.00000   0.00000   0.98000   0.00747
MnM3   0.00000   0.00000   0.00000   0.02000   0.00747
MnM4   0.00000   0.27573   0.50000   0.10000   0.01469
CaM4   0.00000   0.27573   0.50000   0.35500   0.01469
NaM4   0.00000   0.27573   0.50000   0.04000   0.01469
MnM4*   0.00000   0.25212   0.50000   0.09000   0.00925
CaM4*   0.00000   0.25212   0.50000   0.35000   0.00925
NaM4*   0.00000   0.25212   0.50000   0.05000   0.00925
SiT1   0.28276   0.08428   0.29818   0.73000   0.00621
AlT1   0.28276   0.08428   0.29818   0.27000   0.00621
SiT2   0.29062   0.17140   0.80456   1.00000   0.00747
O1   0.11109   0.08493   0.21840   1.00000   0.00836
O2   0.12030   0.17079   0.72608   1.00000   0.00988
F3   0.10460   0.00000   0.71264   1.00000   0.01127
O4   0.36555   0.24881   0.78522   1.00000   0.01381
O5   0.34975   0.13632   0.10108   1.00000   0.01393
O6   0.34669   0.11598   0.59908   1.00000   0.01393
O7   0.34495   0.00000   0.27958   1.00000   0.01254