data_global
_chemical_name_mineral 'Triplite'
loop_
_publ_author_name
'Rea J R'
'Kostiner E'
_journal_name_full 'Acta Crystallographica, Section B'
_journal_volume 28 
_journal_year 1972
_journal_page_first 2525
_journal_page_last 2529
_publ_section_title
;
 The crystal structure of manganese fluorophosphate, Mn2(PO4)F
;
_database_code_amcsd 0009440
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Mn2 P O4 F'
_cell_length_a 13.410
_cell_length_b 6.5096
_cell_length_c 10.094
_cell_angle_alpha 90
_cell_angle_beta 119.99
_cell_angle_gamma 90
_cell_volume 763.169
_exptl_crystal_density_diffrn      3.896
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Mn1   0.05582   0.26660   0.99515
Mn2   0.34421   0.39570   0.64860
P   0.17571   0.40582   0.80601
O1   0.30690   0.08160   0.58280
O2   0.21010   0.14410   0.18800
O3   0.41570   0.03670   0.35820
O4   0.36770   0.28260   0.14510
F   0.01400   0.09700   0.39180
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Mn1 0.00718 0.01076 0.00759 0.00253 0.00365 0.00164
Mn2 0.00847 0.00569 0.00860 -0.00061 0.00468 0.00023
P 0.00431 0.00429 0.00503 -0.00034 0.00175 -0.00012
O1 0.01087 0.00708 0.00747 -0.00088 0.00288 0.00239
O2 0.00690 0.01316 0.01177 0.00188 0.00643 0.00150
O3 0.00847 0.00910 0.00581 -0.00176 0.00010 0.00138
O4 0.01025 0.00517 0.01189 -0.00111 0.00694 0.00012
F 0.01148 0.01696 0.02075 -0.00034 0.00998 -0.00657