data_global _amcsd_formula_title 'O56 P4 Rb0.8 W16' loop_ _publ_author_name 'Giroult J' 'Goreaud M' 'Labbe P' 'Raveau B' _journal_name_full 'Acta Crystallographica, Section B' _journal_volume 36 _journal_year 1980 _journal_page_first 2570 _journal_page_last 2575 _publ_section_title ; Rbx P8 W32 O112: A Tunnel Structure Built up from Re O3-Type Blocks and P2 O7 Groups _cod_database_code 1001237 ; _database_code_amcsd 0009718 _chemical_formula_sum 'Rb.4 P2 W8 O28' _cell_length_a 16.194 _cell_length_b 3.7719 _cell_length_c 17.095 _cell_angle_alpha 90 _cell_angle_beta 93.89 _cell_angle_gamma 90 _cell_volume 1041.794 _exptl_crystal_density_diffrn 6.423 _symmetry_space_group_name_H-M 'P 1 2/c 1' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,-y,1/2+z' '-x,y,1/2-z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy Rb1 0.50000 0.00000 0.50000 0.40000 P1 0.43160 0.40620 0.14560 0.50000 P2 0.43170 0.59360 0.14500 0.50000 W1 0.15094 0.48884 0.21246 1.00000 W2 0.35917 0.53926 0.32722 1.00000 W3 0.25863 0.47253 0.52189 1.00000 W4 0.05192 0.50512 0.40526 1.00000 O1 0.00000 0.50000 0.00000 1.00000 O2 0.21410 0.47840 0.11430 0.50000 O3 0.21340 0.51440 0.11520 0.50000 O4 0.16350 0.49910 0.46130 1.00000 O5 0.05320 0.48850 0.15220 1.00000 O6 0.10330 0.49590 0.30600 1.00000 O7 0.32730 0.46020 0.42480 0.50000 O8 0.32150 0.55370 0.42210 0.50000 O9 0.37690 0.45350 0.07660 0.50000 O10 0.37660 0.05472 0.07780 0.50000 O11 0.26130 0.45210 0.27410 0.50000 O12 0.26360 0.54420 0.27140 0.50000 O13 0.41170 0.44180 0.22280 0.50000 O14 0.41560 0.57240 0.22350 0.50000 O15 0.47870 0.43790 0.37430 0.50000 O16 0.48060 0.54490 0.37300 0.50000 O17 0.26250 0.00370 0.02170 0.50000 O18 0.28390 0.00650 0.01230 0.50000 O19 0.17060 -0.00410 0.20650 0.50000 O20 0.14830 -0.00040 0.21140 0.50000 O21 0.38450 0.01390 0.31790 0.50000 O22 0.35710 0.01020 0.33110 0.50000 O23 0.05570 0.00080 0.40440 1.00000 O24 0.41120 0.00420 0.15370 0.50000