Demesmaekerite Ginderow D, Cesbron F Acta Crystallographica C39 (1983) 824-827 Structure de la demesmaekerite,Pb2Cu5(SeO3)6(UO2)2(OH)6*2H2O Locality: Musoni, Kolwezi, Shaba, Zaire Note: anisoB's from ICSD _database_code_amcsd 0009977 CELL PARAMETERS: 11.9550 10.0390 5.6390 89.780 100.360 91.340 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 665.556 Density (g/cm3): 5.414 MAX. ABS. INTENSITY / VOLUME**2: 26.82871852 RIR: 1.614 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 7.52 12.88 11.7570 1 0 0 2 11.46 7.00 7.7218 -1 1 0 2 11.72 6.90 7.5478 1 1 0 2 15.07 48.53 5.8785 2 0 0 2 15.98 8.15 5.5471 0 0 1 2 16.40 96.86 5.4058 -1 0 1 2 17.31 35.85 5.1242 -2 1 0 2 17.67 4.67 5.0181 0 2 0 2 18.27 1.25 4.8556 0 -1 1 2 18.28 8.33 4.8541 0 1 1 2 18.56 19.53 4.7798 -1 1 1 2 18.72 69.12 4.7391 -1 -1 1 2 18.88 55.66 4.7011 1 0 1 2 19.07 47.14 4.6542 -1 2 0 2 19.39 43.93 4.5773 1 2 0 2 19.93 10.69 4.4539 -2 0 1 2 20.79 1.52 4.2729 1 -1 1 2 20.94 25.71 4.2417 1 1 1 2 21.69 5.59 4.0972 -2 1 1 2 21.97 13.90 4.0454 -2 -1 1 2 22.69 11.64 3.9190 3 0 0 2 23.91 62.11 3.7220 0 -2 1 2 23.92 19.83 3.7206 0 2 1 2 23.95 3.02 3.7148 2 0 1 2 24.07 4.81 3.6967 -1 2 1 2 24.19 6.09 3.6794 -3 1 0 2 24.32 3.99 3.6591 -1 -2 1 2 24.58 25.59 3.6223 3 1 0 2 25.36 6.39 3.5122 -3 0 1 2 25.44 2.49 3.5008 2 -1 1 2 25.69 2.25 3.4671 2 1 1 2 25.85 31.92 3.4472 1 -2 1 2 26.10 8.63 3.4146 1 2 1 2 26.53 4.31 3.3599 -2 2 1 2 26.72 100.00 3.3364 -3 1 1 2 26.99 53.21 3.3030 -2 -2 1 2 27.07 1.61 3.2941 -3 -1 1 2 27.55 46.91 3.2374 -1 3 0 2 27.90 5.73 3.1983 1 3 0 2 29.24 29.23 3.0547 3 2 0 2 29.71 34.90 3.0071 2 -2 1 2 30.14 50.92 2.9648 2 2 1 2 30.20 84.62 2.9598 3 0 1 2 30.41 38.71 2.9392 4 0 0 2 30.44 16.92 2.9368 -2 3 0 2 30.77 1.99 2.9054 -3 2 1 2 31.06 32.33 2.8791 2 3 0 2 31.22 11.82 2.8652 0 -3 1 2 31.23 51.91 2.8643 0 3 1 2 31.30 5.79 2.8579 -1 3 1 2 31.36 17.46 2.8526 3 -1 1 2 31.39 2.91 2.8502 -3 -2 1 2 31.52 12.42 2.8385 -4 1 0 2 31.59 15.27 2.8318 -1 -3 1 2 31.67 8.39 2.8254 3 1 1 2 31.79 38.23 2.8150 -4 0 1 2 31.79 7.76 2.8149 -1 0 2 2 32.28 26.84 2.7735 0 0 2 2 32.71 18.28 2.7381 1 -3 1 2 32.86 2.57 2.7260 -4 1 1 2 33.01 3.77 2.7140 -1 1 2 2 33.01 10.38 2.7135 1 3 1 2 33.10 2.29 2.7067 -1 -1 2 2 33.22 25.10 2.6972 -2 3 1 2 33.24 5.95 2.6951 -4 -1 1 2 33.52 48.24 2.6731 0 1 2 2 33.78 7.31 2.6531 -2 -3 1 2 34.27 19.24 2.6166 -2 1 2 2 34.45 1.04 2.6032 -2 -1 2 2 34.86 54.98 2.5739 -3 3 0 2 35.48 2.36 2.5299 3 2 1 2 35.66 2.37 2.5176 1 -1 2 2 35.69 9.66 2.5159 3 3 0 2 35.76 2.95 2.5111 4 2 0 2 35.79 12.25 2.5091 0 4 0 2 35.86 1.03 2.5045 2 -3 1 2 36.41 7.20 2.4678 2 3 1 2 36.52 4.48 2.4604 -1 2 2 2 36.69 8.61 2.4497 -1 -2 2 2 36.80 1.76 2.4423 1 4 0 2 36.95 9.93 2.4325 -4 -2 1 2 37.04 5.86 2.4271 0 2 2 2 37.10 7.97 2.4232 4 0 1 2 37.16 8.49 2.4196 -3 1 2 2 37.42 9.14 2.4035 -3 -1 2 2 37.64 3.19 2.3899 -2 2 2 2 37.97 15.92 2.3695 -2 -2 2 2 38.28 5.65 2.3514 5 0 0 2 38.29 2.16 2.3506 2 0 2 2 38.96 21.75 2.3117 1 -2 2 2 39.37 6.38 2.2887 2 4 0 2 39.41 1.02 2.2864 0 -4 1 2 39.44 2.96 2.2848 -1 4 1 2 39.46 2.31 2.2838 2 1 2 2 39.57 8.79 2.2778 5 1 0 2 39.68 5.63 2.2717 -5 1 1 2 39.76 11.98 2.2670 -1 -4 1 2 40.28 1.88 2.2392 -3 2 2 2 40.38 2.34 2.2338 -4 3 0 2 40.51 6.15 2.2270 -4 0 2 2 40.59 1.25 2.2224 1 -4 1 2 40.76 22.90 2.2139 -3 -2 2 2 41.05 2.53 2.1987 4 -2 1 2 41.36 2.42 2.1832 4 3 0 2 41.38 11.86 2.1820 -4 1 2 2 41.47 6.91 2.1775 -4 3 1 2 41.69 1.97 2.1662 -4 -1 2 2 41.70 13.75 2.1659 4 2 1 2 41.83 10.48 2.1594 -1 3 2 2 42.06 1.95 2.1484 -1 -3 2 2 42.34 3.21 2.1348 0 3 2 2 42.85 4.15 2.1106 5 2 0 2 43.21 4.67 2.0937 2 -4 1 2 43.22 1.20 2.0934 3 0 2 2 43.34 8.84 2.0879 -5 -2 1 2 44.02 1.99 2.0569 1 -3 2 2 44.21 1.37 2.0486 -4 2 2 2 44.27 8.74 2.0461 1 3 2 2 44.47 2.17 2.0373 5 0 1 2 44.81 7.24 2.0227 -4 -2 2 2 45.15 9.05 2.0083 -3 3 2 2 45.17 9.34 2.0073 0 5 0 2 45.24 12.08 2.0045 5 -1 1 2 45.81 8.60 1.9806 4 -3 1 2 46.05 4.03 1.9711 1 5 0 2 46.28 2.31 1.9617 -6 0 1 2 46.70 17.95 1.9450 -5 3 0 2 46.71 6.09 1.9448 4 3 1 2 46.81 11.21 1.9407 3 -2 2 2 46.99 4.24 1.9336 -6 1 1 2 47.00 3.70 1.9332 -5 -1 2 2 47.04 7.96 1.9320 2 -3 2 2 47.05 9.30 1.9316 -6 1 0 2 47.17 3.69 1.9269 -5 3 1 2 47.26 15.36 1.9234 3 2 2 2 47.43 3.01 1.9170 -6 -1 1 2 47.53 6.36 1.9131 -2 5 0 2 47.79 2.07 1.9032 5 3 0 2 47.85 6.42 1.9010 5 -2 1 2 47.94 1.76 1.8975 3 4 1 2 48.04 5.60 1.8938 -4 4 1 2 48.20 13.39 1.8880 -1 5 1 2 48.21 10.86 1.8877 0 -5 1 2 48.22 3.03 1.8873 0 5 1 2 48.23 9.38 1.8869 4 4 0 2 48.24 1.11 1.8866 -5 -3 1 2 48.25 3.72 1.8863 2 5 0 2 48.44 6.57 1.8792 -1 0 3 2 48.48 3.60 1.8778 -1 4 2 2 48.54 10.21 1.8755 -1 -5 1 2 48.57 1.33 1.8746 5 2 1 2 48.73 5.49 1.8687 -4 3 2 2 48.94 3.93 1.8610 0 -4 2 2 49.05 11.59 1.8574 4 0 2 2 49.17 7.62 1.8530 -4 -4 1 2 49.19 4.72 1.8524 1 -5 1 2 49.30 2.02 1.8484 -2 4 2 2 49.31 1.36 1.8482 -1 1 3 2 49.55 8.74 1.8397 1 5 1 2 49.79 1.36 1.8313 4 -1 2 2 49.84 3.08 1.8296 -2 -4 2 2 49.87 9.68 1.8287 -2 -1 3 2 50.08 1.93 1.8216 4 1 2 2 50.16 1.97 1.8185 0 -1 3 2 50.33 11.21 1.8130 -6 -2 1 2 50.38 3.39 1.8112 6 2 0 2 51.18 7.05 1.7847 3 -3 2 2 51.39 4.37 1.7782 1 0 3 2 51.39 6.25 1.7781 -3 4 2 2 51.43 7.68 1.7767 -3 1 3 2 51.64 3.21 1.7701 3 5 0 2 51.81 5.76 1.7646 3 3 2 2 51.96 1.72 1.7600 4 -4 1 2 52.01 5.73 1.7583 -3 5 1 2 52.02 3.94 1.7579 -1 -2 3 2 52.18 1.91 1.7529 -3 -4 2 2 52.21 3.54 1.7521 1 -1 3 2 52.26 1.70 1.7504 4 -2 2 2 52.28 5.33 1.7497 1 1 3 2 52.53 2.26 1.7420 -2 -2 3 2 52.73 4.30 1.7358 -6 1 2 2 52.73 1.18 1.7358 -5 4 0 2 52.75 6.77 1.7352 0 -2 3 2 52.88 1.67 1.7314 6 -1 1 2 53.01 3.28 1.7276 -3 -5 1 2 53.10 1.66 1.7247 5 3 1 2 53.13 1.26 1.7238 -6 -1 2 2 53.16 3.03 1.7229 -5 4 1 2 53.28 4.64 1.7193 6 1 1 2 53.61 3.18 1.7094 -6 3 1 2 53.69 2.02 1.7073 2 4 2 2 53.88 7.33 1.7015 -3 2 3 2 54.06 4.53 1.6963 5 4 0 2 54.31 4.18 1.6891 -4 1 3 2 54.47 1.92 1.6845 -5 -4 1 2 54.56 8.70 1.6818 -4 -1 3 2 54.65 5.76 1.6796 7 0 0 2 54.65 4.30 1.6795 2 0 3 2 54.74 5.04 1.6770 -7 1 1 2 54.78 4.15 1.6757 -4 5 0 2 54.79 1.34 1.6755 -6 -3 1 2 54.81 10.48 1.6750 3 -5 1 2 55.05 2.26 1.6682 -6 2 2 2 55.19 3.39 1.6643 -7 -1 1 2 55.24 1.82 1.6628 -7 1 0 2 55.40 3.66 1.6584 2 -1 3 2 55.65 9.62 1.6515 -4 -4 2 2 55.68 4.27 1.6507 1 6 0 2 55.70 8.81 1.6503 7 1 0 2 55.79 2.22 1.6478 3 5 1 2 55.82 2.13 1.6471 -6 -2 2 2 55.97 2.83 1.6430 6 2 1 2 56.05 1.07 1.6407 -1 3 3 2 56.25 2.32 1.6353 5 -1 2 2 56.38 1.77 1.6320 -2 3 3 2 56.44 6.38 1.6303 -1 -5 2 2 56.59 2.31 1.6264 0 -5 2 2 56.61 4.67 1.6258 0 5 2 2 56.65 1.11 1.6249 -4 2 3 2 56.88 3.82 1.6187 -2 6 0 2 56.91 10.94 1.6180 0 3 3 2 56.92 4.94 1.6176 -4 -5 1 2 56.93 1.27 1.6175 3 -4 2 2 56.96 5.47 1.6166 -7 2 1 2 57.07 1.87 1.6138 4 3 2 2 57.54 2.10 1.6016 0 -6 1 2 57.56 1.20 1.6013 0 6 1 2 57.77 1.45 1.5960 2 -2 3 2 57.91 1.80 1.5924 1 -5 2 2 58.03 2.97 1.5894 2 2 3 2 58.25 1.33 1.5840 1 5 2 2 58.26 2.48 1.5838 -5 1 3 2 58.34 1.88 1.5818 7 2 0 2 58.50 2.20 1.5777 5 -2 2 2 58.56 6.76 1.5762 -5 -1 3 2 58.62 1.55 1.5748 -2 6 1 2 58.77 3.53 1.5712 1 6 1 2 58.91 9.41 1.5678 -5 4 2 2 58.91 2.87 1.5677 1 3 3 2 58.94 8.19 1.5670 3 0 3 2 58.97 4.89 1.5662 5 4 1 2 59.02 9.23 1.5650 6 -3 1 2 59.11 5.36 1.5629 -6 4 1 2 59.13 5.07 1.5624 5 2 2 2 59.52 8.70 1.5532 -7 1 2 2 59.59 3.69 1.5514 -3 6 0 2 59.63 1.07 1.5505 3 -1 3 2 59.82 1.30 1.5460 3 1 3 2 59.94 6.36 1.5432 -7 -1 2 2 59.99 2.06 1.5420 -6 -3 2 2 60.13 2.01 1.5389 -5 -4 2 2 60.14 1.11 1.5385 6 3 1 2 60.35 3.01 1.5338 2 -6 1 2 60.35 3.50 1.5337 2 -5 2 2 60.39 2.56 1.5329 7 0 1 2 60.45 5.99 1.5314 4 5 1 2 60.49 5.94 1.5306 -4 3 3 2 60.58 2.55 1.5285 -6 -4 1 2 60.63 1.66 1.5273 6 4 0 2 60.70 2.06 1.5258 3 6 0 2 60.70 2.48 1.5257 -7 3 1 2 60.85 9.97 1.5223 -3 6 1 2 60.95 4.85 1.5201 7 -1 1 2 60.98 9.93 1.5193 2 5 2 2 61.17 1.44 1.5151 -7 3 0 2 61.20 3.39 1.5144 -4 -3 3 2 61.62 2.45 1.5052 2 -3 3 2 61.78 9.44 1.5017 -1 -4 3 2 61.84 2.75 1.5004 -2 4 3 2 61.97 1.41 1.4975 -7 -3 1 2 62.00 3.27 1.4968 2 3 3 2 62.24 1.80 1.4917 5 -3 2 2 62.29 1.42 1.4904 -2 -4 3 2 62.37 1.74 1.4888 0 -4 3 2 62.40 1.22 1.4882 0 4 3 2 62.67 1.04 1.4824 4 4 2 2 62.79 2.37 1.4799 6 0 2 2 62.91 1.01 1.4773 -8 1 1 2 63.34 1.31 1.4684 -4 6 0 2 63.37 2.47 1.4678 6 -1 2 2 63.39 1.33 1.4674 3 -6 1 2 63.50 4.91 1.4650 -6 -1 3 2 63.84 3.70 1.4580 3 -5 2 2 63.87 3.64 1.4574 7 2 1 2 63.91 1.32 1.4565 -3 -4 3 2 64.14 1.30 1.4519 4 0 3 2 64.22 1.87 1.4503 6 -4 1 2 64.51 1.09 1.4445 5 -5 1 2 65.14 1.83 1.4321 0 6 2 2 65.21 1.43 1.4307 -7 3 2 2 65.30 2.18 1.4289 -2 6 2 2 65.39 1.24 1.4272 -1 7 0 2 65.54 2.02 1.4244 -4 -6 1 2 65.80 2.48 1.4193 1 7 0 2 65.80 3.09 1.4192 -8 2 0 2 66.15 1.02 1.4127 6 2 2 2 66.24 1.88 1.4108 -7 4 0 2 66.42 5.20 1.4075 -7 -3 2 2 66.42 1.57 1.4075 -2 0 4 2 66.59 3.15 1.4044 -4 -4 3 2 66.67 2.20 1.4028 1 6 2 2 66.88 1.11 1.3990 4 -2 3 2 66.93 1.48 1.3981 -8 1 2 2 67.07 2.61 1.3954 -5 -5 2 2 67.11 3.21 1.3948 -2 1 4 2 67.21 1.52 1.3929 -1 -1 4 2 67.21 2.41 1.3928 -2 -1 4 2 67.39 2.22 1.3897 -8 -1 2 2 67.46 1.13 1.3883 0 -7 1 2 67.48 4.30 1.3880 0 7 1 2 67.55 1.70 1.3868 0 0 4 2 67.58 1.01 1.3863 6 5 0 2 67.61 2.09 1.3856 2 7 0 2 67.79 1.20 1.3823 -1 -7 1 2 67.86 3.06 1.3811 7 4 0 2 68.01 2.46 1.3784 -3 -6 2 2 68.28 5.29 1.3736 0 1 4 2 68.28 3.78 1.3736 -3 -1 4 2 68.29 2.46 1.3735 4 -5 2 2 68.40 1.51 1.3716 -5 6 1 2 68.89 1.40 1.3630 -8 2 2 2 69.23 2.83 1.3571 -8 3 0 2 69.26 1.47 1.3566 -3 7 0 2 69.29 1.14 1.3560 -7 -1 3 2 69.45 1.92 1.3533 4 5 2 2 69.69 1.13 1.3493 1 0 4 2 69.73 1.41 1.3486 -4 6 2 2 69.75 1.34 1.3483 -8 -3 1 2 70.17 2.40 1.3412 -4 1 4 2 70.18 2.59 1.3410 5 0 3 2 70.39 1.57 1.3376 4 -3 3 2 70.45 1.52 1.3366 3 7 0 2 70.45 1.56 1.3365 0 2 4 2 70.55 3.21 1.3349 3 -4 3 2 70.59 1.46 1.3343 7 0 2 2 70.86 6.21 1.3298 -7 2 3 2 71.06 3.85 1.3265 -4 -6 2 2 71.08 2.51 1.3262 4 3 3 2 71.57 1.61 1.3184 -9 1 1 2 71.59 1.66 1.3180 -3 -7 1 2 72.07 1.94 1.3105 -9 -1 1 2 72.21 2.53 1.3083 -4 2 4 2 72.34 1.73 1.3063 6 5 1 2 72.48 4.52 1.3040 1 -2 4 2 72.64 1.18 1.3016 -4 -2 4 2 72.87 2.70 1.2980 -1 3 4 2 73.17 2.43 1.2934 -8 4 1 2 73.29 1.06 1.2916 9 1 0 2 73.57 3.09 1.2874 -6 4 3 2 73.60 8.01 1.2870 -6 6 0 2 73.82 3.72 1.2836 7 2 2 2 73.98 1.10 1.2812 0 -3 4 2 74.27 3.22 1.2771 4 7 0 2 74.41 2.25 1.2749 -1 -7 2 2 74.52 1.09 1.2733 -9 0 2 2 74.87 1.28 1.2682 -6 -4 3 2 74.94 2.62 1.2672 -8 -4 1 2 75.00 1.04 1.2664 -4 -7 1 2 75.04 2.09 1.2658 5 5 2 2 75.36 1.50 1.2612 -2 -7 2 2 75.36 1.47 1.2612 -7 -3 3 2 75.54 1.75 1.2586 -6 -6 1 2 75.58 1.84 1.2581 1 -7 2 2 76.05 2.03 1.2515 -1 6 3 2 76.12 1.41 1.2506 5 -3 3 2 76.25 3.96 1.2486 -4 -3 4 2 76.35 1.18 1.2473 7 -3 2 2 76.81 2.34 1.2410 3 -5 3 2 76.94 1.62 1.2392 -8 4 2 2 77.46 3.48 1.2322 -3 6 3 2 77.56 1.88 1.2309 7 -5 1 2 77.58 1.56 1.2306 -6 -1 4 2 77.66 1.21 1.2295 3 5 3 2 77.74 1.05 1.2284 -1 4 4 2 77.93 1.52 1.2259 -1 -4 4 2 78.10 1.41 1.2237 -6 6 2 2 78.10 1.26 1.2237 0 -8 1 2 78.10 2.57 1.2237 4 7 1 2 78.16 2.11 1.2228 -9 -3 1 2 78.48 2.23 1.2187 -3 4 4 2 78.57 1.77 1.2176 9 -1 1 2 78.69 1.33 1.2160 1 6 3 2 78.77 1.49 1.2150 1 -8 1 2 78.85 1.04 1.2139 0 -4 4 2 78.89 1.33 1.2133 -7 4 3 2 78.94 1.12 1.2128 2 -3 4 2 79.17 1.35 1.2098 -6 2 4 2 79.21 2.26 1.2092 1 8 1 2 79.36 1.84 1.2075 8 -4 1 2 79.50 4.43 1.2056 8 -1 2 2 79.54 3.05 1.2052 3 -2 4 2 79.60 2.19 1.2043 -7 6 1 2 79.72 1.42 1.2029 -3 8 0 2 79.84 2.63 1.2013 6 -5 2 2 80.10 2.37 1.1981 6 2 3 2 80.25 1.04 1.1962 -4 -7 2 2 80.39 1.60 1.1945 -10 0 1 2 80.93 1.22 1.1879 -4 -6 3 2 81.09 2.27 1.1859 8 4 1 2 81.34 1.04 1.1829 -10 -1 1 2 81.36 1.60 1.1827 9 2 1 2 81.48 2.01 1.1812 6 5 2 2 81.72 1.52 1.1784 -7 0 4 2 81.83 1.39 1.1771 -8 -3 3 2 81.86 3.00 1.1768 -7 -6 1 2 81.92 1.01 1.1760 3 7 2 2 81.98 1.56 1.1753 4 0 4 2 82.45 2.70 1.1698 -9 4 0 2 82.70 3.32 1.1669 6 -3 3 2 82.90 2.26 1.1646 10 1 0 2 83.21 1.91 1.1611 -5 4 4 2 83.29 2.44 1.1601 -9 -1 3 2 83.30 1.83 1.1600 -10 0 2 2 83.38 4.19 1.1591 3 3 4 2 83.67 1.61 1.1558 2 -4 4 2 83.71 2.85 1.1553 -4 8 1 2 84.07 1.47 1.1513 -7 2 4 2 84.12 1.34 1.1508 -1 -5 4 2 84.14 1.53 1.1506 -10 2 0 2 84.25 2.14 1.1493 -5 -4 4 2 84.36 2.47 1.1481 -1 8 2 2 84.38 1.79 1.1479 9 4 0 2 84.57 2.32 1.1459 -9 4 2 2 84.62 1.00 1.1453 -9 2 3 2 84.64 2.09 1.1450 7 0 3 2 84.84 1.21 1.1429 0 8 2 2 84.90 1.15 1.1422 7 -6 1 2 85.49 1.84 1.1358 -10 2 2 2 85.73 1.86 1.1332 0 -7 3 2 86.30 1.34 1.1272 1 8 2 2 86.38 2.25 1.1263 -3 8 2 2 86.71 2.08 1.1229 4 -8 1 2 86.80 2.43 1.1220 -8 -4 3 2 86.81 3.40 1.1219 -6 7 2 2 87.17 1.68 1.1182 1 -7 3 2 87.17 2.27 1.1182 6 -6 2 2 87.31 1.28 1.1168 -1 1 5 2 87.35 2.31 1.1164 -3 -7 3 2 88.16 1.71 1.1082 5 5 3 2 88.35 1.61 1.1063 10 -1 1 2 88.38 1.64 1.1060 -7 -3 4 2 88.80 1.45 1.1018 7 5 2 2 88.89 2.36 1.1010 10 1 1 2 89.39 1.57 1.0961 -3 2 5 2 89.40 1.61 1.0960 -1 -2 5 2 89.59 1.34 1.0942 2 -7 3 2 89.92 1.07 1.0910 -8 2 4 2 89.99 1.00 1.0904 9 4 1 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.