data_global
_chemical_name_mineral 'Pyrobelonite'
loop_
_publ_author_name
'Kolitsch U'
_journal_name_full 'Acta Crystallographica, Section E'
_journal_volume 57 
_journal_year 2001
_journal_page_first i119
_journal_page_last i121
_publ_section_title
;
 Refinement of pyrobelonite, PbMnIIVO4(OH), a member of the descloizite group
;
_database_code_amcsd 0010371
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Pb Mn V O5 H'
_cell_length_a 7.646
_cell_length_b 6.1790
_cell_length_c 9.507
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 449.155
_exptl_crystal_density_diffrn      5.828
_symmetry_space_group_name_H-M 'P n m a'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,z'
  '-x,1/2+y,-z'
  '1/2-x,1/2+y,1/2+z'
  '1/2+x,1/2-y,1/2-z'
  '1/2+x,y,1/2-z'
  '1/2-x,-y,1/2+z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Pb   0.13286   0.25000   0.17753   0.01086
Mn   0.00000   0.00000   0.50000   0.00650
V   0.36513   0.75000   0.31118   0.00422
O1   0.18820   0.75000   0.42740   0.00820
O2   0.54070   0.75000   0.41330   0.01780
O3   0.37280   0.51280   0.20990   0.01030
O-h4   0.15650   0.25000   0.42440   0.00720
H   0.24300   0.25000   0.46500   0.02000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Pb 0.01011 0.01714 0.00532 0.00000 0.00006 0.00000
Mn 0.00890 0.00490 0.00570 -0.00070 0.00020 0.00080
V 0.00490 0.00480 0.00290 0.00000 0.00120 0.00000
O1 0.00990 0.00870 0.00580 0.00000 0.00280 0.00000
O2 0.00830 0.03400 0.01060 0.00000 -0.00380 0.00000
O3 0.01370 0.00840 0.00890 0.00120 0.00270 -0.00110
O-h4 0.00500 0.00680 0.00980 0.00000 -0.00310 0.00000