data_global _chemical_name_mineral 'Vysotskite' loop_ _publ_author_name 'Gaskell T F' _journal_name_full 'Zeitschrift fur Kristallographie' _journal_volume 96 _journal_year 1937 _journal_page_first 203 _journal_page_last 213 _publ_section_title ; The structure of braggite and palladium sulphide ; _database_code_amcsd 0010567 _chemical_compound_source 'Synthetic' _chemical_formula_sum 'Pd S' _cell_length_a 6.43 _cell_length_b 6.43 _cell_length_c 6.63 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 274.117 _exptl_crystal_density_diffrn 6.711 _symmetry_space_group_name_H-M 'P 42/m' loop_ _space_group_symop_operation_xyz 'x,y,z' 'y,-x,1/2-z' '-y,x,1/2+z' 'x,y,-z' '-x,-y,z' '-y,x,1/2-z' 'y,-x,1/2+z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Pd1 0.00000 0.00000 0.25000 Pd2 0.00000 0.50000 0.00000 Pd3 0.47500 0.25000 0.00000 S 0.20000 0.32000 0.22000