data_global
_chemical_name_mineral 'Zincolibethenite'
loop_
_publ_author_name
'Williams P A'
'Leverett P'
'Birch W D'
'Hibbs D E'
'Kilitsch U'
'Mihajlovic T'
_journal_name_full 'Australian Journal of Mineralogy'
_journal_volume 12 
_journal_year 2006
_journal_page_first 3
_journal_page_last 7
_publ_section_title
;
 Zinc-rich zincolibethenite from Broken Hill, New South Wales
 Note: z-coordinate of O3 altered by communication with authors, April 2010
;
_database_code_amcsd 0012060
_chemical_compound_source 'Block 14 open cut, Broken Hill, New South Wales, Australia'
_chemical_formula_sum 'Zn1.06 Cu.94 (P.98 As.02) O5 H'
_cell_length_a 8.323
_cell_length_b 8.251
_cell_length_c 5.861
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 402.493
_exptl_crystal_density_diffrn      3.992
_symmetry_space_group_name_H-M 'P n n m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2-y,1/2+z'
  '1/2-x,1/2+y,1/2-z'
  '1/2-x,1/2+y,1/2+z'
  '1/2+x,1/2-y,1/2-z'
  'x,y,-z'
  '-x,-y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Zn1   0.36060   0.37090   0.50000   1.00000   0.00800
Cu   0.00000   0.50000   0.25090   0.94000   0.01000
Zn2   0.00000   0.50000   0.25090   0.06000   0.01000
P   0.23350   0.25290   0.00000   0.98000   0.00600
As   0.23350   0.25290   0.00000   0.02000   0.00600
O1   0.10980   0.11310   0.00000   1.00000   0.01100
O2   0.13290   0.41310   0.00000   1.00000   0.00900
O3   0.34050   0.24250   0.21190   1.00000   0.01100
O-h   0.11670   0.39370   0.50000   1.00000   0.00900
H   0.09200   0.30700   0.50000   1.00000   0.03800