data_global
_chemical_name_mineral 'Rinkite'
loop_
_publ_author_name
'Camara F'
'Sokolova E'
'Hawthorne F C'
_journal_name_full 'Mineralogical Magazine'
_journal_volume 75 
_journal_year 2011
_journal_page_first 2755
_journal_page_last 2774
_publ_section_title
;
 From structure topology to chemical composition. XII. Titanium silicates:
 the crystal chemistry of rinkite, Na2Ca4REETi(Si2O7)2OF3
 Note: sample YuksFe
;
_database_code_amcsd 0018564
_chemical_compound_source 'Yuskpor Mt., Khibiny, Kola, Russia'
_chemical_formula_sum 'Ca3.58 Dy.02 Gd.02 Sm.04 Nd.18 Pr.06 Ce.46 La.18 Y.12 Sr.14 Ba.02 (Ti.85 Nb.12 Zr.03) Na2.2 Si4 O15.18 F2.82'
_cell_length_a 7.4263
_cell_length_b 5.6774
_cell_length_c 18.8261
_cell_angle_alpha 90
_cell_angle_beta 101.390
_cell_angle_gamma 90
_cell_volume 778.115
_exptl_crystal_density_diffrn      3.497
_symmetry_space_group_name_H-M 'P 1 21/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,1/2+z'
  '-x,1/2+y,1/2-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
CaMH   0.09489   0.65997   0.19196   0.66000   0.01210
DyMH   0.09489   0.65997   0.19196   0.01000   0.01210
GdMH   0.09489   0.65997   0.19196   0.01000   0.01210
SmMH   0.09489   0.65997   0.19196   0.01000   0.01210
NdMH   0.09489   0.65997   0.19196   0.06000   0.01210
PrMH   0.09489   0.65997   0.19196   0.02000   0.01210
CeMH   0.09489   0.65997   0.19196   0.15000   0.01210
LaMH   0.09489   0.65997   0.19196   0.06000   0.01210
YMH   0.09489   0.65997   0.19196   0.04000   0.01210
CaAP   0.59781   0.66229   0.19035   0.73000   0.01400
SrAP   0.59781   0.66229   0.19035   0.07000   0.01400
BaAP   0.59781   0.66229   0.19035   0.01000   0.01400
SmAP   0.59781   0.66229   0.19035   0.01000   0.01400
NdAP   0.59781   0.66229   0.19035   0.03000   0.01400
PrAP   0.59781   0.66229   0.19035   0.01000   0.01400
CeAP   0.59781   0.66229   0.19035   0.08000   0.01400
LaAP   0.59781   0.66229   0.19035   0.03000   0.01400
YAP   0.59781   0.66229   0.19035   0.02000   0.01400
TiMO(1)   0.00000   0.00000   0.00000   0.85000   0.02470
NbMO(1)   0.00000   0.00000   0.00000   0.12000   0.02470
ZrMO(1)   0.00000   0.00000   0.00000   0.03000   0.02470
NaMO(2)   0.50000   0.00000   0.00000   1.00000   0.01720
NaMO(3)   0.75299   0.50080   0.00011   0.60000   0.02580
CaMO(3)   0.75299   0.50080   0.00011   0.40000   0.02580
Si(1)   0.34990   0.15320   0.13975   1.00000   0.01160
Si(2)   0.78452   0.15270   0.13747   1.00000   0.01040
O(1)   0.21690   0.14960   0.06121   1.00000   0.02050
O(2)   0.83300   0.13940   0.05802   1.00000   0.02010
O(3)   0.33660   0.39500   0.18369   1.00000   0.01900
O(4)   0.84310   0.39510   0.17974   1.00000   0.02180
O(5)   0.33310   0.93050   0.19113   1.00000   0.01570
O(6)   0.85080   0.93220   0.18995   1.00000   0.01690
O(7)   0.55750   0.13990   0.12029   1.00000   0.02640
OXOM   0.02470   0.70260   0.06143   0.59000   0.02220
FXOM   0.02470   0.70260   0.06143   0.41000   0.02220
FXOA   0.52410   0.65660   0.06327   1.00000   0.02850