Manganoarrojadite-(KNa) Lykova I, Rowe R, Poirier G, Helwig K, Friis H Mineralogical Magazine 84 (2020) 932-940 Manganoarrojadite-(KNa), KNa5MnFe13Al(PO4)11(PO3OH)(OH)2, a new arrojadite-group mineral from the Palermo No. 1 mine, New Hampshire, USA Locality: Palermo No. 1 mine, New Hampshire, USA _database_code_amcsd 0020956 16.5345 10.04057 24.6261 90 105.891 90 Cc atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) K1 .99862 .50858 .24413 .874 .0352 .0238 .0329 .0562 .0035 .0232 .0055 Na1 .0040 .9977 .99843 .0228 .0283 .0119 .0211 .0047 -.0051 .0022 Na2 .8736 .4867 .87784 .0443 .081 .0148 .0182 .0127 -.0190 -.0042 Na3 .29495 .4459 .04226 .0277 .0241 .0339 .0209 .0080 -.0012 .0072 Na4 .12151 .5116 .12095 .0221 .0367 .0127 .0120 .0043 -.0020 .0005 Na5 .02189 .8183 .77109 .752 .0258 .0220 .0243 .0290 -.0081 .0035 -.0036 Mn .23041 .78586 .97856 .88 .01277 .0124 .0119 .0157 -.0032 .0069 -.0025 Ca .23041 .78586 .97856 .12 .01277 .0124 .0119 .0157 -.0032 .0069 -.0025 Fe1 .22726 .11699 .97591 .7 .01155 .0097 .0105 .0153 .0015 .0048 .0034 Mn1 .22726 .11699 .97591 .3 .01155 .0097 .0105 .0153 .0015 .0048 .0034 Fe2 .28938 .51216 .22829 .55 .01184 .0155 .0095 .0086 -.0019 -.0001 -.0006 Mn2 .28938 .51216 .22829 .3 .01184 .0155 .0095 .0086 -.0019 -.0001 -.0006 Mg2 .28938 .51216 .22829 .15 .01184 .0155 .0095 .0086 -.0019 -.0001 -.0006 Fe3 .71499 .49329 .76594 .7 .01128 .0116 .0111 .0096 .0011 .0002 .0003 Mn3 .71499 .49329 .76594 .3 .01128 .0116 .0111 .0096 .0011 .0002 .0003 Fe4 .11254 .01474 .13706 .7 .01063 .0115 .0096 .0103 .0005 .0022 -.0013 Mg4 .11254 .01474 .13706 .3 .01063 .0115 .0096 .0103 .0005 .0022 -.0013 Fe5 .89613 .98862 .85777 .7 .01060 .0107 .0092 .0105 -.0005 .0007 -.0008 Mg5 .89613 .98862 .85777 .3 .01060 .0107 .0092 .0105 -.0005 .0007 -.0008 Fe6 .02154 .75148 .90041 .9 .00914 .0076 .0086 .0112 .0011 .0025 .0016 Mg6 .02154 .75148 .90041 .1 .00914 .0076 .0086 .0112 .0011 .0025 .0016 Fe7 .97754 .24724 .09333 .85 .00769 .0076 .0072 .0080 .0011 .0017 .0002 Mg7 .97754 .24724 .09333 .15 .00769 .0076 .0072 .0080 .0011 .0017 .0002 Fe8 .96960 .74714 .09624 .00800 .0071 .0092 .0074 -.0004 .0015 .0003 Fe9 .03563 .26024 .89825 .00847 .0065 .0094 .0092 .0005 .0016 .0003 Fe10 .20642 .30592 .84961 .6 .01099 .0117 .0125 .0086 -.0003 .0024 -.0001 Mn10 .20642 .30592 .84961 .4 .01099 .0117 .0125 .0086 -.0003 .0024 -.0001 Fe11 .29818 .19937 .14574 .4 .01431 .0128 .0215 .0076 .0027 .0012 -.0009 Mn11 .29818 .19937 .14574 .6 .01431 .0128 .0215 .0076 .0027 .0012 -.0009 Fe12 .28452 .78871 .15165 .6 .00970 .0084 .0132 .0072 -.0027 .0016 .0014 Mn12 .28452 .78871 .15165 .3 .00970 .0084 .0132 .0072 -.0027 .0016 .0014 Mg12 .28452 .78871 .15165 .1 .00970 .0084 .0132 .0072 -.0027 .0016 .0014 Fe13 .22309 .29804 .34013 .4 .01247 .0123 .0168 .0077 .0051 .0018 -.0015 Mn13 .22309 .29804 .34013 .6 .01247 .0123 .0168 .0077 .0051 .0018 -.0015 Al1 .00363 .50120 .99823 .00546 .0058 .0053 .0054 .0001 .0018 -.0001 P1 .11752 .99477 .86640 .00653 .0060 .0066 .0071 -.0001 .0020 -.0003 P2 .42104 .49673 .16091 .00998 .0118 .0090 .0114 -.0021 .0071 -.0012 P3 .13261 .54033 .92281 .00668 .0064 .0066 .0076 .0002 .0029 -.0006 P4 .87365 .46858 .07432 .00595 .0053 .0067 .0059 -.0003 .0016 .0006 P5 .12924 .25278 .03774 .0063 .0061 .0065 .0067 .0013 .0024 .0007 P6 .37905 .25198 .96040 .0060 .0054 .0060 .0064 .0005 .0011 .0007 P7 .10895 .76482 .04545 .00644 .0073 .0066 .0055 -.0010 .0018 -.0006 P8 .90048 .23202 .95247 .00591 .0055 .0050 .0073 -.0004 .0018 -.0006 P9 .87083 .27580 .78599 .0077 .0081 .0081 .0065 .0001 .0012 .0004 P10 .13229 .72527 .20905 .00690 .0070 .0066 .0066 .0005 .0010 -.0005 P11 .85859 .70521 .79109 .0097 .0100 .0069 .0095 .0010 -.0020 -.0009 P12 .14301 .29528 .20257 .0090 .0107 .0068 .0074 .0009 -.0010 .0000 O1 .4803 .5613 .13091 .0136 .0122 .0118 .0193 -.0011 .0087 .0008 O2 .0295 .9407 .86616 .0105 .0080 .0078 .0169 -.0004 .0055 .0036 O3 .3893 .3646 .13296 .0105 .0112 .0090 .0125 -.0002 .0053 -.0024 O4 .1140 .1472 .86031 .0110 .0111 .0068 .0167 -.0011 .0066 .0006 O5 .6452 .4262 .81890 .0146 .0192 .0147 .0142 -.0026 .0116 -.0063 O6 .1826 .9606 .92221 .0131 .0137 .0133 .0101 .0010 -.0004 -.0003 O7 .4773 .4732 .22429 .0313 .042 .039 .0111 -.013 .0051 .0015 O8 .3488 .5824 .1651 .0297 .027 .0147 .057 .0007 .028 -.0036 O9 .0509 .5586 .94200 .0078 .0090 .0079 .0082 .0006 .0051 .0014 O10 .95251 .4458 .05341 .0080 .0072 .0088 .0085 .0018 .0032 .0006 O11 .1263 .4060 .89316 .0113 .0103 .0088 .0174 -.0023 .0082 -.0033 O12 .8824 .5997 .10541 .0110 .0138 .0078 .0128 -.0006 .0062 -.0033 O13 .1288 .6612 .88252 .0112 .0108 .0108 .0153 .0019 .0092 .0057 O14 .3747 .8468 .11179 .0100 .0106 .0110 .0089 .0010 .0037 .0029 O15 .2119 .5599 .97063 .0141 .0106 .0187 .0110 -.0025 -.0004 -.0022 O16 .2923 .9669 .02541 .0108 .0084 .0112 .0103 -.0006 -.0014 .0014 O17 .0849 .1664 .07187 .0123 .0128 .0115 .0152 .0019 .0082 .0048 O18 .4181 .3335 .92143 .0095 .0097 .0070 .0140 .0008 .0067 .0022 O19 .0989 .3975 .03522 .0091 .0082 .0095 .0091 .0022 .0013 .0007 O20 .90897 .6075 .96329 .0075 .0083 .0048 .0087 .0010 .0012 .0001 O21 .1116 .1916 .97755 .0128 .0172 .0117 .0091 .0050 .0031 -.0015 O22 .4003 .3166 .01864 .0112 .0132 .0126 .0073 .0034 .0023 -.0012 O23 .2248 .2470 .06207 .0135 .0063 .0144 .0186 .0013 .0017 .0050 O24 .2819 .2484 .93595 .0115 .0065 .0140 .0139 .0009 .0024 .0040 O25 .0528 .6420 .04699 .0081 .0107 .0066 .0072 -.0031 .0027 -.0005 O26 .9564 .3560 .95192 .0070 .0073 .0049 .0091 -.0011 .0025 -.0014 O27 .0745 .8701 .07879 .0102 .0106 .0101 .0104 -.0013 .0036 -.0042 O28 .9378 .1291 .91995 .0094 .0111 .0062 .0121 -.0017 .0050 -.0019 O29 .0971 .8141 .98479 .0106 .0159 .0086 .0075 -.0006 .0034 .0019 O30 .9052 .1836 .01178 .0128 .0178 .0127 .0081 -.0068 .0037 -.0006 O31 .2019 .7353 .07080 .0123 .0051 .0160 .0150 .0000 .0011 -.0033 O32 .8096 .2666 .92154 .0132 .0070 .0136 .0164 .0019 -.0014 -.0009 O33 .9527 .3219 .82734 .0145 .0092 .0182 .0131 -.0027 -.0016 .0023 O34 .0505 .6792 .16745 .0117 .0126 .0126 .0073 -.0018 -.0018 .0006 O35 .8683 .6791 .22681 .0159 .0182 .0204 .0090 .0053 .0038 -.0003 O36 .1381 .6721 .26732 .0157 .0214 .0159 .0081 -.0064 .0012 .0024 O37 .8621 .1233 .78913 .0228 .035 .0102 .0162 -.0018 -.0054 .0027 O38 .1363 .8793 .20893 .0162 .0228 .0063 .0142 -.0022 -.0036 -.0009 O39 .7967 .3383 .80454 .0155 .0100 .0209 .0157 .0056 .0037 -.0006 O40 .2055 .6687 .18801 .0156 .0086 .0250 .0141 .0008 .0048 -.0040 O41 .9456 .6661 .82875 .0159 .0130 .0163 .0139 .0075 -.0037 -.0029 O42 .0599 .3371 .16176 .0125 .0137 .0109 .0096 .0004 -.0023 -.0016 O43 .8481 .3492 .23286 .0396 .057 .036 .0127 -.033 -.0117 .0130 O44 .1450 .3426 .26156 .0268 .040 .025 .0087 .0159 -.0048 -.0064 O45 .8525 .8585 .79108 .0138 .0205 .0045 .0138 .0021 .0002 -.0014 O46 .1531 .1436 .20252 .0139 .0203 .0089 .0089 .0009 -.0024 -.0001 O47 .7882 .6482 .81551 .0230 .0124 .0181 .034 -.0045 -.0022 .0103 O48 .2159 .3596 .18281 .0209 .0125 .0208 .027 -.0039 .0014 .0112 O49 .2352 .9957 .13510 .0190 .0116 .0250 .022 -.0032 .0080 -.0086 O50 .2727 .5013 .86372 .0116 .0083 .0125 .0134 -.0001 .0017 .0002