data_global
_chemical_name_mineral 'Zincowoodwardite'
loop_
_publ_author_name
'Witzke T'
'Raade G'
_journal_name_full 'Neues Jahrbuch fur Mineralogie, Monatshefte'
_journal_volume 2000 
_journal_year 2000
_journal_page_first 455
_journal_page_last 465
_publ_section_title
;
 Zincowoodwardite, [Zn1-x Alx(OH)2][(SO4)x/2(H2O)n], a new mineral of the hydrotalcite group
 Note: polytype Zincowoodwardite-1T
;
_database_code_amcsd 0014907
_chemical_compound_source 'Hilarion mine, Kamariza, near Laurion, Greece'
_chemical_formula_sum '(Zn.625 Al.375) S.188 O2.686 H2.376'
_cell_length_a 3.063
_cell_length_b 3.063
_cell_length_c 8.91
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 72.394
_exptl_crystal_density_diffrn      2.348
_symmetry_space_group_name_H-M 'P -3'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'y,-x+y,-z'
  '-x+y,-x,z'
  '-x,-y,-z'
  '-y,x-y,z'
  'x-y,x,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Zn   0.00000   0.00000   0.00000   0.62500
Al   0.00000   0.00000   0.00000   0.37500
S   0.00000   0.00000   0.46400   0.09400
O-H1   0.33333   0.66667   0.11000   1.00000
O2   0.26730  -0.26730   0.42000   0.08300
Wat3   0.00000   0.00000   0.60000   0.09400