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Ardennite-(As) |
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Donnay G, Allmann R |
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Acta Crystallographica B24 (1968) 845-855 |
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Si3O10 groups in the crystal structure of ardennite |
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_database_code_amcsd 0009340 |
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8.7126 5.8108 18.5214 90 90 90 *Pnmm |
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0 .25 .25 |
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atom x y z occ Biso |
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Mn1 .9441 .25 .1554 .765 .95 |
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Ca1 .9441 .25 .1554 .235 .95 |
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Mn2 .3956 .75 .1600 .95 |
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Al1 0 0 0 .62 |
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Al2 .5 0 0 .76 |
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Mg .6787 -.0016 .25 .50 .96 |
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Al .6787 -.0016 .25 .15 .96 |
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Fe .6787 -.0016 .25 .10 .96 |
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Cu .6787 -.0016 .25 .03 .96 |
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Si1 .7641 .75 .0970 .37 |
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Si2 .2766 .25 .0951 .59 |
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Si3 .3412 .25 .25 .66 |
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As .0426 .75 .25 .905 .45 |
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V .0426 .75 .25 .095 .45 |
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O1 .1284 .0265 -.0828 .82 |
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O2 .6241 -.0207 -.0833 .81 |
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O3 .1127 .25 .0526 .86 |
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O4 .6169 .75 .0415 1.91 |
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O5 .9299 -.0068 .25 1.02 |
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O6 .4431 .0146 .25 1.06 |
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O7 .6817 .75 .1776 0.19 |
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O8 .2232 .25 .1805 1.78 |
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O9 .1540 .75 .1763 .36 |
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OH1 .1128 .75 .0323 .95 |
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OH2 .6149 .25 .0356 .35 |
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OH3 .6973 .25 .1817 .91 |
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Ardennite-(As) |
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Nagashima M, Armbruster T |
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Mineralogical Magazine 74 (2010) 55-71 |
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Ardennite, tiragalloite and medaite: structural control of (As5+,V5+,Si4+)O4 |
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tetrahedra in silicates |
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Locality: Salm-Chateau, Ardennes, Belgium |
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_database_code_amcsd 0019900 |
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8.7163 5.8131 18.5199 90 90 90 *Pnmm |
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0 .25 .25 |
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atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) |
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MnA1 .94486 .25 .155325 .790 .01014 .01181 .00971 .00890 0 .00230 0 |
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CaA1 .94486 .25 .155325 .210 .01014 .01181 .00971 .00890 0 .00230 0 |
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MnA2 .39566 .75 .159978 .865 .00949 .01232 .00849 .00766 0 -.00129 0 |
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CaA2 .39566 .75 .159978 .135 .00949 .01232 .00849 .00766 0 -.00129 0 |
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AlM1 0 0 0 .00570 .0060 .0051 .0060 .00041 .0003 -.00012 |
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AlM2 .5 0 0 .00698 .0076 .0065 .0068 .00010 .0003 -.00012 |
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AlM3 .67916 -.00151 .25 .511 .00767 .0100 .0061 .0069 -.00061 0 0 |
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MgM3 .67916 -.00151 .25 .42 .00767 .0100 .0061 .0069 -.00061 0 0 |
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CuM3 .67916 -.00151 .25 .035 .00767 .0100 .0061 .0069 -.00061 0 0 |
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VM3 .67916 -.00151 .25 .034 .00767 .0100 .0061 .0069 -.00061 0 0 |
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SiT1 .76474 .75 .09695 .00363 .0032 .0047 .0030 0 .00001 0 |
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SiT2 .27693 .25 .09523 .00626 .0060 .0068 .0059 0 -.00004 0 |
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SiT3 .34294 .25 .25 .00808 .0096 .0078 .0069 0 0 0 |
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AsT4 .04243 .75 .25 .833 .00637 .00671 .00574 .00666 0 0 0 |
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VT4 .04243 .75 .25 .127 .00637 .00671 .00574 .00666 0 0 0 |
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SiT4 .04243 .75 .25 .04 .00637 .00671 .00574 .00666 0 0 0 |
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O1 .12881 .02530 -.08282 .00851 .0088 .0085 .0082 -.0008 .0010 -.0007 |
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O2 .62411 -.01905 -.08292 .00852 .0100 .0079 .0077 .0008 .0017 .0007 |
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O3 .11086 .25 .05260 .0088 .0071 .0100 .0094 0 -.0008 0 |
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O4 .61717 .75 .04181 .0084 .0079 .0084 .0091 0 -.0014 0 |
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O5 .92758 -.0081 .25 .0123 .0128 .0098 .0145 .0021 0 0 |
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O6 .44487 .0110 .25 .0122 .0150 .0110 .0106 .0018 0 0 |
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O7 .68104 .75 .17757 .0115 .0113 .0155 .0077 0 .0025 0 |
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O8 .22317 .25 .18086 .0101 .0115 .0123 .0066 0 .0016 0 |
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O9 .15183 .75 .17639 .0135 .0118 .0189 .0098 0 .0018 0 |
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O10 .11259 .75 .03231 .0079 .0077 .0088 .0071 0 -.0007 0 |
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O11 .61341 .25 .03609 .0080 .0073 .0094 .0075 0 .0000 0 |
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O12 .69784 .25 .18253 .0125 .0109 .0179 .0086 0 .0005 0 |
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H10 .126 .75 .0845 .05 |
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H11 .7188 .25 .018 .05 |
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H12 .657 .25 .1337 .05 |
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| Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure (permalink) |
  |
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Ardennite-(As) |
|
Nagashima M, Armbruster T |
|
Mineralogical Magazine 74 (2010) 55-71 |
|
Ardennite, tiragalloite and medaite: structural control of (As5+,V5+,Si4+)O4 |
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tetrahedra in silicates |
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Locality: Vernetto mine, Val Lanzo, Torino, Piedmont, Italy |
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_database_code_amcsd 0019901 |
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8.7452 5.8314 18.5891 90 90 90 *Pnmm |
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0 .25 .25 |
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atom x y z occ Uiso U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3) |
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MnA1 .94617 .25 .15546 .57 .01326 .0167 .0098 .0133 0 .00391 0 |
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CaA1 .94617 .25 .15546 .43 .01326 .0167 .0098 .0133 0 .00391 0 |
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MnA2 .39662 .75 .15995 .80 .01241 .0172 .0079 .0121 0 -.00152 0 |
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CaA2 .39662 .75 .15995 .20 .01241 .0172 .0079 .0121 0 -.00152 0 |
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AlM1 0 0 0 .878 .0080 .0084 .0058 .0097 .0003 .0008 .0000 |
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FeM1 0 0 0 .122 .0080 .0084 .0058 .0097 .0003 .0008 .0000 |
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AlM2 .5 0 0 .00810 .0088 .0058 .0097 -.0003 .0003 -.0004 |
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MgM3 .68069 -.00158 .25 .54 .0086 .0109 .0054 .0096 -.0002 0 0 |
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AlM3 .68069 -.00158 .25 .279 .0086 .0109 .0054 .0096 -.0002 0 0 |
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MnM3 .68069 -.00158 .25 .181 .0086 .0109 .0054 .0096 -.0002 0 0 |
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SiT1 .76328 .75 .09619 .00791 .0075 .0070 .0093 0 .0000 0 |
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SiT2 .27823 .25 .09517 .00858 .0085 .0071 .0102 0 -.0002 0 |
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SiT3 .34387 .25 .25 .0090 .0109 .0058 .0102 0 0 0 |
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AsT4 .04264 .75 .25 .730 .00988 .0115 .0057 .0124 0 0 0 |
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SiT4 .04264 .75 .25 .270 .00988 .0115 .0057 .0124 0 0 0 |
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O1 .13036 .0263 -.08177 .0103 .0109 .0071 .0129 -.0010 .0015 -.0011 |
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O2 .62384 -.0193 -.08283 .0102 .0107 .0073 .0125 .0005 .0016 .0001 |
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O3 .1113 .25 .05398 .0124 .0101 .0148 .0125 0 -.0012 0 |
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O4 .6163 .75 .04145 .0102 .0099 .0079 .0128 0 -.0017 0 |
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O5 .9287 -.0117 .25 .0155 .0145 .0089 .0231 .0033 0 0 |
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O6 .4435 .0122 .25 .0128 .0162 .0068 .0155 .0025 0 0 |
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O7 .6795 .75 .17642 .0130 .0124 .0145 .0120 0 .0022 0 |
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O8 .2258 .25 .18087 .0115 .0123 .0122 .0099 0 .0007 0 |
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O9 .1502 .75 .17743 .0162 .0169 .0163 .0153 0 .0004 0 |
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O10 .1118 .75 .03336 .0105 .0082 .0106 .0126 0 -.0007 0 |
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O11 .6139 .25 .03572 .0100 .0081 .0090 .0128 0 .0006 0 |
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O12 .6979 .25 .18221 .0126 .0127 .0138 .0114 0 .0010 0 |
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H10 .123 .75 .0857 .05 |
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H11 .715 .25 .014 .05 |
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H12 .657 .25 .1332 .05 |
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| Download AMC data (View Text File) Download CIF data (View Text File) Download diffraction data (View Text File) View JMOL 3-D Structure (permalink) |
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