Na2(Mn5.26Na0.74)Ge6O20 Redhammer G J, Roth G, Topa D, Amthauer G Acta Crystallographica C64 (2008) i21-i26 Synthetic aenigmatite analog Na2(Mn5.26Na0.74)Ge6O20: structure and crystal chemical considerations Locality: synthetic T = 295 K _database_code_amcsd 0010341 CELL PARAMETERS: 10.5578 11.1532 9.1833 106.707 95.809 124.367 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 806.042 Density (g/cm3): 4.564 MAX. ABS. INTENSITY / VOLUME**2: 8.380994618 RIR: 0.598 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 9.27 2.96 9.5402 -1 1 0 2 10.59 8.82 8.3564 0 1 0 2 10.67 9.34 8.2928 0 0 1 2 11.45 5.96 7.7266 0 -1 1 2 12.38 11.86 7.1482 -1 0 1 2 14.79 1.03 5.9915 -1 1 1 2 16.80 1.72 5.2775 1 -2 1 2 17.72 6.46 5.0047 -1 -1 1 2 17.96 37.96 4.9403 0 1 1 2 18.60 9.28 4.7701 -2 2 0 2 18.69 8.51 4.7476 -2 1 1 2 19.30 3.56 4.5991 1 1 0 2 19.37 9.89 4.5835 0 -2 1 2 19.50 9.27 4.5519 0 -1 2 2 20.61 64.80 4.3100 2 -2 1 2 20.68 65.94 4.2944 -2 0 1 2 21.27 8.25 4.1782 0 2 0 2 21.43 8.62 4.1464 0 0 2 2 22.58 1.12 3.9377 1 -1 2 2 22.69 2.19 3.9197 1 -2 2 2 23.02 67.71 3.8633 0 -2 2 2 24.71 1.32 3.6030 2 -3 1 2 24.91 1.83 3.5741 -2 0 2 2 25.07 15.20 3.5520 -2 3 0 2 25.27 17.46 3.5238 -2 1 2 2 25.46 22.26 3.4982 -3 2 0 2 25.78 8.05 3.4562 1 1 1 2 26.82 12.20 3.3241 -3 1 1 2 27.13 16.59 3.2872 1 0 2 2 27.15 1.03 3.2840 -2 -1 1 2 27.39 1.67 3.2561 1 -3 2 2 27.65 64.94 3.2267 0 2 1 2 27.74 60.03 3.2157 0 1 2 2 28.42 2.19 3.1406 3 -2 1 2 28.78 9.49 3.1026 2 -3 2 2 28.89 10.95 3.0909 -2 -1 2 2 29.13 8.33 3.0651 3 -3 1 2 29.23 41.10 3.0558 0 -3 1 2 29.41 16.98 3.0375 1 2 0 2 29.47 41.57 3.0309 0 -1 3 2 29.61 15.47 3.0170 2 1 0 2 29.68 16.59 3.0103 2 -1 2 2 29.71 26.71 3.0073 -2 3 1 2 29.82 27.15 2.9957 -2 2 2 2 31.03 17.26 2.8818 -3 3 1 2 31.35 17.62 2.8531 -1 2 2 2 31.63 35.63 2.8288 3 -1 1 2 32.13 84.47 2.7856 2 -4 1 2 32.13 4.86 2.7855 0 3 0 2 32.23 18.99 2.7774 -3 2 2 2 32.32 21.73 2.7698 -1 3 1 2 32.39 3.76 2.7643 0 0 3 2 32.46 84.35 2.7584 -2 0 3 2 32.63 9.82 2.7443 -3 0 2 2 32.70 27.47 2.7389 3 0 0 2 32.89 8.87 2.7229 1 -1 3 2 33.19 2.13 2.6993 -1 -2 3 2 33.59 1.47 2.6681 1 -3 3 2 33.91 1.22 2.6437 3 -3 2 2 33.92 6.08 2.6425 -2 4 0 2 33.97 73.61 2.6387 2 -4 2 2 34.10 16.35 2.6289 -3 4 0 2 34.23 64.28 2.6198 -2 -1 3 2 34.24 4.26 2.6190 -2 1 3 2 34.61 20.24 2.5920 -1 1 3 2 34.64 100.00 2.5897 -4 2 0 2 34.76 17.77 2.5808 3 -2 2 2 34.83 27.03 2.5755 0 -3 3 2 35.01 1.36 2.5633 1 -4 2 2 35.46 12.56 2.5312 2 1 1 2 35.52 11.02 2.5274 2 0 2 2 35.91 60.62 2.5010 -2 -2 1 2 35.91 1.28 2.5010 -4 3 1 2 36.02 58.97 2.4934 2 -2 3 2 36.37 18.16 2.4701 0 2 2 2 36.46 6.43 2.4644 3 -4 2 2 36.55 5.13 2.4583 4 -3 1 2 36.64 4.12 2.4525 -4 1 1 2 36.68 5.78 2.4503 -1 -3 1 2 37.22 10.40 2.4157 -1 4 0 2 37.33 9.61 2.4087 -3 1 3 2 37.64 11.27 2.3894 -3 -1 1 2 37.72 14.40 2.3851 -4 4 0 2 37.90 13.36 2.3738 -4 2 2 2 38.02 7.27 2.3665 4 -2 1 2 38.04 6.65 2.3654 -4 1 0 2 38.29 1.08 2.3504 4 -4 1 2 38.50 1.18 2.3385 -4 1 2 2 39.00 11.34 2.3098 2 -4 3 2 39.12 10.43 2.3025 -2 -2 3 2 39.31 19.22 2.2917 0 -4 2 2 39.60 19.54 2.2760 0 -2 4 2 40.30 16.21 2.2380 -4 4 1 2 40.41 14.56 2.2321 -4 3 2 2 40.59 4.80 2.2224 3 -5 1 2 41.20 4.41 2.1908 -1 0 4 2 41.23 5.96 2.1897 -3 -1 3 2 41.25 6.75 2.1885 3 -3 3 2 41.31 5.85 2.1855 2 -5 1 2 41.45 1.71 2.1785 1 -2 4 2 41.58 2.39 2.1719 2 -5 2 2 41.75 5.78 2.1635 -2 0 4 2 41.97 2.15 2.1526 -2 -1 4 2 42.43 5.53 2.1306 4 -1 1 2 43.29 2.66 2.0898 -5 3 1 2 43.85 1.51 2.0648 1 2 2 2 43.97 5.83 2.0593 -2 5 0 2 44.09 5.59 2.0541 4 0 0 2 44.10 5.84 2.0537 4 -2 2 2 44.39 5.29 2.0407 -2 1 4 2 44.71 9.84 2.0270 -2 -3 2 2 44.85 8.97 2.0209 2 -3 4 2 44.95 3.71 2.0168 1 -5 1 2 44.99 1.01 2.0149 -1 -3 4 2 45.10 1.54 2.0104 4 -5 2 2 45.10 1.35 2.0103 2 2 1 2 45.21 2.81 2.0057 -3 0 4 2 45.23 1.02 2.0048 2 0 3 2 45.39 1.75 1.9981 -4 0 3 2 45.39 4.38 1.9980 -3 -2 2 2 45.59 5.99 1.9897 -4 4 2 2 45.95 3.16 1.9749 3 -5 3 2 46.13 2.90 1.9679 -1 -4 2 2 46.21 1.01 1.9644 -2 4 2 2 46.27 6.26 1.9622 0 3 2 2 46.34 1.32 1.9595 -2 3 3 2 46.37 6.06 1.9581 0 2 3 2 47.04 2.53 1.9316 0 -4 4 2 47.05 6.12 1.9314 -4 5 1 2 47.13 1.79 1.9285 -3 -1 4 2 47.29 4.98 1.9223 -4 3 3 2 48.80 1.72 1.8660 -4 -1 1 2 48.82 1.86 1.8654 4 -3 3 2 49.12 3.15 1.8548 4 0 1 2 49.14 3.45 1.8540 4 -1 2 2 49.18 4.42 1.8527 -2 5 1 2 49.25 2.97 1.8502 0 4 1 2 49.40 1.98 1.8451 -5 4 2 2 49.40 3.80 1.8451 3 -6 2 2 49.53 4.72 1.8404 -2 2 4 2 49.55 3.27 1.8398 0 1 4 2 49.56 1.33 1.8392 5 -4 2 2 49.84 1.99 1.8297 4 -5 3 2 49.91 1.05 1.8274 3 2 0 2 49.93 1.79 1.8264 -1 3 3 2 50.03 2.65 1.8231 -5 5 1 2 50.04 5.47 1.8228 3 -4 4 2 50.05 3.31 1.8226 -4 -1 3 2 50.07 2.71 1.8217 -1 -1 5 2 50.35 4.15 1.8122 2 -5 4 2 50.49 4.44 1.8075 -2 -3 4 2 50.56 1.63 1.8053 -1 4 2 2 50.75 2.85 1.7990 2 -6 2 2 51.01 3.03 1.7903 0 -5 1 2 51.28 2.93 1.7817 -2 -1 5 2 51.45 2.17 1.7760 -4 6 0 2 51.48 4.20 1.7753 0 -1 5 2 51.52 1.72 1.7738 -3 -2 4 2 51.71 2.60 1.7677 1 -3 5 2 51.72 3.19 1.7674 -5 3 3 2 51.90 1.83 1.7619 -4 2 4 2 52.14 1.49 1.7542 -2 0 5 2 52.25 2.70 1.7508 -1 2 4 2 52.30 4.90 1.7491 -6 4 0 2 52.37 5.13 1.7469 -6 3 1 2 52.63 1.20 1.7391 -5 0 2 2 52.84 4.35 1.7326 -4 5 2 2 52.97 4.39 1.7287 -4 4 3 2 52.99 5.63 1.7281 2 2 2 2 52.99 4.16 1.7281 3 -2 4 2 53.07 5.59 1.7258 2 1 3 2 53.55 1.55 1.7113 -5 6 0 2 54.01 1.55 1.6979 -6 5 0 2 54.04 1.83 1.6969 4 -6 3 2 54.05 2.63 1.6966 -1 5 1 2 54.14 4.59 1.6941 0 -5 4 2 54.18 2.17 1.6929 -6 3 2 2 54.31 5.90 1.6893 0 -4 5 2 54.40 1.44 1.6865 -4 -1 4 2 54.41 2.67 1.6863 6 -4 1 2 54.51 3.05 1.6835 -6 2 1 2 54.58 1.32 1.6815 5 -2 2 2 54.59 2.90 1.6810 1 -6 2 2 54.64 1.63 1.6797 -5 0 3 2 54.86 24.91 1.6736 -2 6 0 2 54.96 4.01 1.6706 -3 -1 5 2 55.05 4.14 1.6682 -3 -3 3 2 55.14 1.32 1.6658 -2 -4 3 2 55.30 1.09 1.6613 2 -4 5 2 55.38 4.72 1.6591 -6 5 1 2 55.40 23.74 1.6585 -2 1 5 2 55.48 5.35 1.6563 -6 4 2 2 55.53 2.87 1.6549 -4 6 1 2 55.83 6.34 1.6468 0 3 3 2 55.90 2.81 1.6449 -4 3 4 2 55.96 3.15 1.6433 5 0 0 2 55.98 2.79 1.6426 5 -5 3 2 56.00 4.50 1.6420 -4 -2 2 2 56.03 3.56 1.6413 4 -4 4 2 56.13 4.65 1.6387 6 -3 1 2 56.16 4.69 1.6379 -6 2 0 2 56.21 25.72 1.6364 4 0 2 2 56.29 1.85 1.6344 -3 -3 1 2 56.75 3.32 1.6221 -2 -4 1 2 57.03 1.04 1.6150 -1 -5 3 2 57.09 3.05 1.6133 2 -2 5 2 57.25 1.20 1.6092 -1 1 5 2 58.00 1.38 1.5900 -6 6 0 2 58.01 2.73 1.5899 5 -3 3 2 58.05 9.45 1.5889 6 -6 1 2 58.31 1.06 1.5825 -6 3 3 2 58.32 2.19 1.5821 4 -7 1 2 58.38 9.60 1.5807 -6 2 3 2 58.89 1.02 1.5682 -6 1 1 2 58.93 1.55 1.5672 -4 1 5 2 59.60 5.60 1.5513 4 -6 4 2 59.60 1.03 1.5512 5 -7 1 2 59.83 1.97 1.5457 3 -7 3 2 59.85 5.68 1.5454 -4 -2 4 2 59.85 32.43 1.5453 0 -5 5 2 60.06 2.38 1.5403 -1 6 0 2 60.31 2.59 1.5347 4 -7 3 2 60.32 1.65 1.5345 -2 6 1 2 60.40 35.89 1.5326 6 -6 2 2 60.47 1.57 1.5310 3 -5 5 2 60.52 30.73 1.5299 -4 5 3 2 60.54 1.19 1.5295 3 -3 5 2 60.56 3.07 1.5288 -1 -2 6 2 60.60 1.09 1.5279 0 -6 2 2 60.61 11.95 1.5278 0 -6 3 2 60.64 1.84 1.5270 -5 -1 1 2 60.72 34.94 1.5253 -6 1 3 2 60.79 1.89 1.5236 -2 2 5 2 60.83 2.25 1.5228 -4 -1 5 2 61.01 40.71 1.5187 2 4 0 2 61.07 10.68 1.5173 0 -3 6 2 61.36 37.27 1.5109 2 -1 5 2 61.69 2.79 1.5037 -4 6 2 2 61.95 3.77 1.4979 -4 4 4 2 62.67 1.55 1.4824 2 -6 5 2 62.74 1.19 1.4808 -7 3 1 2 62.82 1.89 1.4792 -2 -4 5 2 62.84 2.00 1.4787 3 1 3 2 62.85 2.46 1.4786 0 -6 1 2 62.86 3.45 1.4784 0 -6 4 2 63.10 1.37 1.4734 -3 -3 5 2 63.20 4.26 1.4713 0 -4 6 2 63.44 1.66 1.4663 0 -1 6 2 63.62 1.30 1.4625 -6 2 4 2 63.85 1.00 1.4577 1 -6 5 2 64.02 1.85 1.4543 -6 7 0 2 64.47 1.88 1.4453 -6 3 4 2 64.48 1.37 1.4451 6 -7 2 2 64.54 1.21 1.4440 -1 0 6 2 64.91 2.75 1.4367 6 -6 3 2 64.94 1.28 1.4359 -6 1 4 2 65.17 3.16 1.4315 -6 0 3 2 65.21 7.91 1.4308 6 -4 3 2 65.25 8.59 1.4299 -6 0 1 2 65.26 1.13 1.4297 -2 -5 3 2 65.38 1.13 1.4274 -4 7 1 2 65.72 1.67 1.4208 1 -7 3 2 65.89 1.16 1.4175 -4 3 5 2 66.18 1.17 1.4121 -3 -2 6 2 66.19 1.13 1.4119 -3 -4 4 2 66.46 3.82 1.4067 0 4 3 2 66.58 3.58 1.4046 0 3 4 2 67.02 5.99 1.3963 4 -6 5 2 67.06 2.69 1.3956 -6 7 1 2 67.14 4.98 1.3942 -4 -3 4 2 67.26 4.69 1.3920 2 4 1 2 67.44 2.87 1.3887 -6 4 4 2 67.57 1.19 1.3863 7 -3 1 2 67.58 1.74 1.3861 1 -1 6 2 67.59 4.93 1.3859 2 0 5 2 67.62 1.48 1.3855 -5 -2 2 2 67.65 2.93 1.3849 -2 6 2 2 67.75 1.46 1.3832 -4 -3 1 2 67.96 1.63 1.3793 4 -3 5 2 67.97 2.27 1.3792 -4 0 6 2 68.04 2.34 1.3780 -2 3 5 2 68.52 1.05 1.3694 6 0 0 2 68.54 1.02 1.3691 6 -3 3 2 68.66 1.21 1.3670 5 -1 3 2 68.77 2.02 1.3651 7 -7 1 2 69.01 9.25 1.3609 -4 -1 6 2 69.04 2.02 1.3604 3 -7 5 2 69.43 2.92 1.3536 -7 6 2 2 69.63 6.29 1.3502 -4 6 3 2 69.78 5.67 1.3478 -4 5 4 2 70.16 2.47 1.3413 -7 5 3 2 70.37 1.58 1.3379 -1 4 4 2 70.83 1.57 1.3304 -1 -5 6 2 70.85 2.50 1.3300 -1 5 3 2 70.89 5.17 1.3293 4 -7 5 2 71.13 1.39 1.3255 -7 7 1 2 71.18 6.33 1.3247 -4 -3 5 2 71.34 1.38 1.3221 6 -5 4 2 71.40 1.55 1.3211 -6 -1 2 2 71.78 1.48 1.3151 0 -7 3 2 71.90 1.57 1.3131 5 -5 5 2 72.13 1.45 1.3095 -4 2 6 2 72.24 1.00 1.3078 -7 2 4 2 72.30 2.95 1.3068 -1 3 5 2 72.32 1.83 1.3066 3 -6 6 2 72.41 1.99 1.3051 0 -3 7 2 72.42 4.79 1.3050 -6 3 5 2 73.02 3.16 1.2958 2 3 3 2 73.11 3.05 1.2943 2 2 4 2 73.29 1.27 1.2917 -7 4 4 2 73.37 1.06 1.2904 6 -4 4 2 73.72 1.17 1.2852 -1 6 2 2 73.80 1.12 1.2840 -1 -1 7 2 74.62 1.14 1.2718 -2 -3 7 2 75.07 4.34 1.2653 -4 -4 3 2 75.24 3.78 1.2629 4 -5 6 2 76.09 1.51 1.2509 2 -7 6 2 76.12 1.34 1.2505 -4 -4 2 2 76.26 1.56 1.2486 -2 -5 6 2 76.39 1.13 1.2467 4 -4 6 2 77.25 1.32 1.2351 0 4 4 2 77.29 1.05 1.2344 -2 -6 4 2 77.99 1.30 1.2251 -2 -6 2 2 78.25 1.62 1.2217 -2 -4 7 2 78.56 1.13 1.2177 2 -3 7 2 79.87 1.97 1.2009 2 5 1 2 80.02 1.53 1.1991 -2 7 2 2 80.34 1.74 1.1951 2 0 6 2 80.45 1.32 1.1938 0 7 0 2 80.56 1.46 1.1924 -2 3 6 2 81.19 1.26 1.1847 0 0 7 2 81.69 1.71 1.1787 -6 5 5 2 84.12 1.38 1.1507 -4 4 6 2 84.27 1.24 1.1491 -4 2 7 2 84.48 1.77 1.1468 4 2 3 2 84.56 1.64 1.1459 4 1 4 2 86.30 1.14 1.1272 -7 2 6 2 86.82 2.59 1.1218 4 -5 7 2 87.75 1.84 1.1123 6 2 0 2 87.92 1.48 1.1105 6 -3 5 2 88.10 1.06 1.1087 5 2 2 2 89.46 1.04 1.0954 -2 7 3 2 89.52 1.96 1.0948 -6 -2 6 2 89.91 1.18 1.0911 -2 4 6 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.